| 1 | POULIDOR Raymond | 35y + 339d | 1972 | Stage 1b (ITT) | Montjuich - Montjuich |
| 2 | MARTÍN Manuel | 34y + 295d | 1966 | Stage 2 | Barcelona - Manlleu |
| 3 | MARTINELLO Silvio | 34y + 68d | 1997 | Stage 4 | Andorra la Vella - Santa Coloma de Gramanet |
| 4 | FONTANELLI Fabiano | 33y + 336d | 1999 | Stage 5a | Cerdañola - Cerdañola |
| 5 | EDO Ángel | 33y + 235d | 2004 | Stage 5 | Solsona - Parets del Vallès |
| 6 | YÁÑEZ Felipe | 33y + 59d | 1986 | Stage 2 | Ripoll - Andorra la Vella |
| 7 | WIJNANDS Ad | 33y + 18d | 1992 | Stage 5 | Calafell - Lloret de Mar |
| 8 | ZBERG Beat | 32y + 318d | 2004 | Stage 2 | Lloret de Mar - Empuriabrava |
| 9 | ZABEL Erik | 32y + 264d | 2003 | Stage 5 | Bagá - Vic |
| 10 | KARSTENS Gerben | 32y + 73d | 1974 | Stage 4b (ITT) | Corbins - Balaguer |
| 11 | RECIO José | 32y + 56d | 1989 | Stage 2 | Calafell - Lleida |
| 12 | JÄRMANN Rolf | 32y + 52d | 1998 | Stage 2 | Lloret de Mar - Castelló d'Empúries |
| 13 | GUERINI Giuseppe | 32y + 41d | 2002 | Stage 3 | Castelló de Ampurias - Castelló de Ampurias |
| 14 | KELLY Sean | 31y + 304d | 1988 | Stage 4b (ITT) | Lleida - Lleida |
| 15 | AJA Gonzalo | 31y + 259d | 1978 | Stage 3 | Valls - Sant Miquel d'Engolasters |
| 16 | BAFFI Adriano | 31y + 230d | 1994 | Stage 5a | Santa Coloma de Gramanet - Sant Cugat del Vallès |
| 17 | WÜST Marcel | 31y + 228d | 1999 | Stage 1 | Lloret de Mar - Lloret de Mar |
| 18 | TAMAMES Agustín | 31y + 158d | 1976 | Stage 5 | L'Hospitalet de Llobregat - Santa Eulàlia de Ronçana |
| 19 | FREULER Urs | 31y + 135d | 1990 | Stage 3 | Martinet de Cerdanya - Santa Coloma de Gramenet |
| 20 | JALABERT Laurent | 31y + 114d | 2000 | Stage 5a | Cerdanyola del Vallès - Cerdanyola del Vallès |
| 21 | BERTRAN Antonio | 31y + 113d | 1965 | Stage 2 | Barcelona - Hospitalet de Llobregat |
| 22 | PERURENA Domingo | 31y + 110d | 1975 | Stage 5 | Roda de Ter - Malgrat de Mar |
| 23 | BRAUN Gregor | 31y + 82d | 1987 | Stage 1b | Parets - Girona |
| 24 | EKIMOV Viatcheslav | 31y + 50d | 1997 | Stage 3 | L'Hospitalet de Llobregat - Andorra la Vella |
| 25 | RIOTTE Raymond | 31y + 36d | 1971 | Stage 4b | Girona - Manlleu |
| 26 | LÓPEZ RODRÍGUEZ José Manuel | 31y + 30d | 1971 | Stage 3 | Sabadell - Malgrat de Mar |
| 27 | DOMÍNGUEZ Juan Carlos | 30y + 348d | 2002 | Stage 2a | Lloret de Mar - Empuriabrava |
| 28 | MERCKX Eddy | 30y + 282d | 1976 | Stage 4b (ITT) | L'Hospitalet de Llobregat - L'Hospitalet de Llobregat |
| 29 | COLOTTI Jean-Claude | 30y + 266d | 1992 | Stage 1 | Lloret de Mar - Lloret de Mar |
| 30 | PAGNIN Roberto | 30y + 260d | 1993 | Stage 3 | Llívia - Lloret de Mar |
| 31 | KIRSIPUU Jaan | 30y + 251d | 2000 | Stage 5a | Cerdanyola del Vallès - Cerdanyola del Vallès |
| 32 | LEIPHEIMER Levi | 30y + 153d | 2004 | Stage 4 | Palau Solita i Plegamans - El Port del Comte |
| 33 | LASA Miguel María | 30y + 145d | 1978 | Stage 2 | Cunit - Reus |
| 34 | MONTOYA Jesús | 30y + 112d | 1994 | Stage 5a | Santa Coloma de Gramanet - Sant Cugat del Vallès |
| 35 | PÉREZ FRANCÉS José | 30y + 94d | 1967 | Stage 4 | Barcelona - L'Hospitalet de Llobregat |
| 36 | BONTEMPI Guido | 30y + 67d | 1990 | Stage 1b | Torredembarra - Lleida |
| 37 | MURN Uroš | 30y + 41d | 2005 | Stage 1 | Lloret de Mar - Lloret de Mar |
| 38 | DELISLE Raymond | 30y + 16d | 1973 | Stage 1 | Malgrat de Mar - Berga |
| 39 | DELGADO Pedro | 29y + 339d | 1990 | Stage 2 | Lleida - Andorra la Vella |
| 40 | GASTÓN Iñaki | 29y + 303d | 1993 | Stage 2 | Montblanc - Andorra la Vella |
| 41 | ZÜLLE Alex | 29y + 265d | 1998 | Stage 5a | L'Hospitalet de Llobregat - Cerdanyola del Vallès |
| 42 | PEETERS Ludo | 29y + 230d | 1983 | Stage 4 | Lleida - Badalona |
| 43 | FRIGO Dario | 29y + 190d | 2003 | Stage 4 | Parets del Vallès - Coll de Pal |
| 44 | ZILIOLI Italo | 29y + 182d | 1971 | Stage 5 | Manlleu - Soldeu |
| 45 | MARTÍN PERDIGUERO Miguel Ángel | 29y + 165d | 2002 | Stage 4 | Bagá - Vic |
| 46 | GUTIÉRREZ Alfonso | 29y + 122d | 1991 | Stage 2 | Lloret de Mar - Parets del Vallès |
| 47 | ALOMAR Jaime | 29y + 95d | 1967 | Stage 2 | Barcelona - Castelldefels |
| 48 | HERMANS Mathieu | 29y + 75d | 1992 | Stage 2a | Pineda de Mar - Santa Coloma de Gramenet |
| 49 | PANTANI Marco | 29y + 69d | 1999 | Stage 2 | Lloret de Mar - Empuriabrava |
| 50 | ZANOTTI Marco | 29y + 64d | 2003 | Stage 3 | Castelló de Ampurias - Parets |