| 1 | 1997 | 0:02 | ESCARTÍN Fernando | CASERO Ángel Luis |
| 2 | 1977 | 0:02 | MAERTENS Freddy | DE MUYNCK Johan |
| 3 | 1985 | 0:03 | MILLAR Robert | KELLY Sean |
| 4 | 1959 | 0:03 | BOTELLA Salvador | MANZANEQUE Fernando |
| 5 | 2015 | 0:04 | PORTE Richie | VALVERDE Alejandro |
| 6 | 2014 | 0:04 | RODRÍGUEZ Joaquim | CONTADOR Alberto |
| 7 | 1993 | 0:04 | MEJIA Alvaro | FONDRIEST Maurizio |
| 8 | 1990 | 0:04 | CUBINO Laudelino | LEJARRETA Marino |
| 9 | 2016 | 0:07 | QUINTANA Nairo | CONTADOR Alberto |
| 10 | 1998 | 0:08 | BUENAHORA Hernan | TOTSCHNIG Georg |
| 11 | 1969 | 0:08 | DÍAZ Mariano | BITOSSI Franco |
| 12 | 2010 | 0:10 | RODRÍGUEZ Joaquim | TONDO Xavier |
| 13 | 2019 | 0:14 | LÓPEZ Miguel Ángel | YATES Adam |
| 14 | 2009 | 0:15 | VALVERDE Alejandro | MARTIN Dan |
| 15 | 1956 | 0:15 | UTSET Aniceto | ITURAT Vicente |
| 16 | 2008 | 0:16 | CÉSAR VELOSO Gustavo | URÁN Rigoberto |
| 17 | 2013 | 0:17 | MARTIN Dan | RODRÍGUEZ Joaquim |
| 18 | 1992 | 0:19 | INDURAIN Miguel | ROMINGER Tony |
| 19 | 2005 | 0:20 | POPOVYCH Yaroslav | PIEPOLI Leonardo |
| 20 | 2011 | 0:23 | CONTADOR Alberto | SCARPONI Michele |
| 21 | 2004 | 0:28 | MARTÍN PERDIGUERO Miguel Ángel | KARPETS Vladimir |
| 22 | 2018 | 0:29 | VALVERDE Alejandro | QUINTANA Nairo |
| 23 | 2002 | 0:31 | HERAS Roberto | GARMENDIA Aitor |
| 24 | 1962 | 0:32 | KARMANY Antonio | MARTÍN Manuel |
| 25 | 2001 | 0:33 | BELOKI Joseba | GONZÁLEZ DE GALDEANO Igor |
| 26 | 1968 | 0:33 | MERCKX Eddy | GIMONDI Felice |
| 27 | 1967 | 0:37 | ANQUETIL Jacques | GÓMEZ Antonio |
| 28 | 2000 | 0:41 | JIMÉNEZ José María | SEVILLA Óscar |
| 29 | 2003 | 0:43 | PECHARROMÁN José Antonio | HERAS Roberto |
| 30 | 1982 | 0:51 | FERNÁNDEZ Alberto | MUÑOZ Pedro |
| 31 | 1999 | 0:57 | BELTRÁN Manuel | HERAS Roberto |
| 32 | 1991 | 1:00 | INDURAIN Miguel | DELGADO Pedro |
| 33 | 2017 | 1:03 | VALVERDE Alejandro | CONTADOR Alberto |
| 34 | 1970 | 1:05 | BITOSSI Franco | GALDOS Francisco |
| 35 | 1996 | 1:08 | ZÜLLE Alex | JONKER Patrick |
| 36 | 1961 | 1:17 | DUEZ Henri | NICOLAU Juan Jorge |
| 37 | 1966 | 1:23 | DEN HARTOG Arie | ANQUETIL Jacques |
| 38 | 2012 | 1:30 | ALBASINI Michael | SÁNCHEZ Samuel |
| 39 | 1957 | 1:41 | LOROÑO Jesús | BOTELLA Salvador |
| 40 | 1954 | 1:43 | SERENA Walter | SANT Alberto |
| 41 | 1952 | 1:44 | POBLET Miguel | GROSSO Adolfo |
| 42 | 1926 | 2:06 | FONTAN Victor | MIQUEL Mució |
| 43 | 1936 | 2:22 | CAÑARDO Mariano | BONDUEL Frans |
| 44 | 1941 | 2:24 | ANDRÉS Francisco Antonio | CANALS Andrés |
| 45 | 1944 | 2:37 | CASAS Miguel | LANGARICA Dalmacio |
| 46 | 1953 | 2:46 | BOTELLA Salvador | MASIP Francesco |
| 47 | 1911 | 2:46 | MASDEU Sebastián | MAGDALENA José |
| 48 | 1929 | 2:51 | CAÑARDO Mariano | AERTS Jean |
| 49 | 1927 | 3:01 | FONTAN Victor | CAÑARDO Mariano |
| 50 | 1950 | 3:09 | GELABERT Antonio | SERRA José |
| 51 | 1964 | 3:13 | CARRARA Joseph | FABBRI Pasquale |
| 52 | 1951 | 3:17 | VOLPI Primo | MASIP Francesco |
| 53 | 1949 | 3:46 | ROL Émile | POBLET Miguel |
| 54 | 1958 | 3:51 | VAN GENECHTEN Richard | MAS Gabriel |
| 55 | 1960 | 3:56 | POBLET Miguel | PÉREZ José |
| 56 | 1932 | 4:02 | CAÑARDO Mariano | PIEMONTESI Domenico |
| 57 | 1946 | 4:18 | BERRENDERO Julián | WEILENMANN Gottfried |
| 58 | 1940 | 4:26 | DIDIER Christophe | CLEMENS Mathias |
| 59 | 1931 | 4:45 | CARDONA Salvador | CAÑARDO Mariano |
| 60 | 1943 | 4:47 | BERRENDERO Julián | MIRÓ Vicente |
| 61 | 1947 | 5:01 | RODRÍGUEZ Emilio | GUAL Miguel |
| 62 | 1925 | 5:10 | MIQUEL Mució | JANER Jaime |
| 63 | 1963 | 5:30 | NOVALES Joseph | SOLER Angelino |
| 64 | 1928 | 5:52 | CAÑARDO Mariano | MIQUEL Mució |
| 65 | 1934 | 6:06 | ROGORA Bernardo | DELOOR Alfons |
| 66 | 1965 | 6:14 | GÓMEZ Antonio | ECHEVARRÍA Carlos |
| 67 | 1939 | 6:39 | CAÑARDO Mariano | CHÁFER Diego |
| 68 | 1948 | 7:31 | RODRÍGUEZ Emilio | BRESCI Giulio |
| 69 | 1942 | 8:21 | EZQUERRA Federico | BERRENDERO Julián |
| 70 | 1945 | 9:32 | RUIZ Bernardo | GIMENO Juan |
| 71 | 1924 | 10:13 | MIQUEL Mució | MONTEYS Teodoro |
| 72 | 1935 | 10:48 | CAÑARDO Mariano | EZQUERRA Federico |
| 73 | 1955 | 11:03 | GÓMEZ José | COMPANY Gabriel |
| 74 | 1923 | 13:10 | VILLE Maurice | PELLETIER José |
| 75 | 1913 | 18:13 | MARTÍ Juan | CRESPO Antonio |
| 76 | 1920 | 20:06 | PELLETIER José | NAT Jose |
| 77 | 1930 | 22:05 | CAÑARDO Mariano | MAUREL Marcel |
| 78 | 1933 | 31:59 | BOVET Alfredo | MORELLI Ambrogio |
| 79 | 1912 | 44:16 | MAGDALENA José | MARTI Joaquin |