| 1 | 1982 | COCQUYT Patrick | 13:35 | Stage 7b | Cambrils - Salou |
| 2 | 1980 | LAURENS Marcel | 10:29 | Stage 3 | Espluga de Francolí - Mollet |
| 3 | 1951 | POBLET Miguel | 8:31 | Stage 12 | Vilanova y Geltrú - Barcelona |
| 4 | 1985 | CALDENTEY Juan | 8:21 | Stage 7b | Tortosa - Salou |
| 5 | 1988 | GONZALEZ Arsenio | 7:27 | Stage 5 | Bagá - Super Espot |
| 6 | 1979 | JOURDAN Christian | 7:23 | Stage 6 | Bagá - Playa de Aro |
| 7 | 1953 | ZAMPINI Donato | 6:48 | Stage 7 | Tarragona - Berga |
| 8 | 1985 | MARTÍNEZ Juan | 6:13 | Stage 5 | Barcelona - Lleida |
| 9 | 1952 | DE RYCK Isidoor | 5:45 | Stage 5 | Tortosa - Valls |
| 10 | 1979 | FUCHS Josef | 5:40 | Stage 4 | Ager - Espot |
| 11 | 1966 | DE MUNSTER Eric | 5:06 | Stage 7 | Lloret de Mar - Vallpineda |
| 12 | 1983 | RECIO José | 4:48 | Stage 6 | Girona - Manresa |
| 13 | 1987 | MULLER Jörg | 4:20 | Stage 6 | Tremp - Manresa |
| 14 | 1953 | ALOMAR Francisco | 4:07 | Stage 2 | Girona - Granollers |
| 15 | 1964 | CARRARA Joseph | 4:05 | Stage 3a | Lloret de Mar - Ribas de Freser |
| 16 | 1951 | NAVARRO Luis | 4:05 | Stage 6 | Reus - Tortosa |
| 17 | 1970 | MESA José Manuel | 3:41 | Stage 6 | Alp - Girona |
| 18 | 1953 | JANSSENS Marcel | 3:38 | Stage 8 | Berga - Barcelona |
| 19 | 1946 | BERRENDERO Julián | 3:34 | Stage 3 | Figueres - Puigcerda |
| 20 | 1987 | ALONSO Marino | 3:32 | Stage 7 | Manresa - Olot |
| 21 | 1969 | URIBEZUBIA Juan María | 3:27 | Stage 4a | Balaguer - Flix |
| 22 | 1948 | SAURA Gabriel | 3:16 | Stage 3 | Figueres - Vic |
| 23 | 1971 | MORI Primo | 2:57 | Stage 5a | Santa Coloma de Gramanet - Barcelona |
| 24 | 1948 | GUAL Miguel | 2:42 | Stage 2 | Badalona - Figueres |
| 25 | 1980 | LÓPEZ José Luis | 2:42 | Stage 2 | Lérida - Espluga de Francolí |
| 26 | 1963 | ALOMAR Jaime | 2:40 | Stage 7a | Tortosa - Salomó |
| 27 | 2019 | DE GENDT Thomas | 2:38 | Stage 1 | Calella - Calella |
| 28 | 1955 | PACHECO Miguel | 2:34 | Stage 5 | Perpignan - Les Escaldes |
| 29 | 2008 | CHAVANEL Sylvain | 2:32 | Stage 4 | Ascó - El Vendrell |
| 30 | 1948 | BERTOCCHI Elio | 2:30 | Stage 5 | Andorra la Vella - Lérida |
| 31 | 1952 | VIDAL PORCAR José | 2:30 | Stage 9 | Vilanova y Geltrú - Berga |
| 32 | 1966 | ANQUETIL Jacques | 2:25 | Stage 6b (ITT) | Sant Feliu de Guíxols - Lloret de Mar |
| 33 | 1972 | SANTISTEBAN Juan Manuel | 2:14 | Stage 4 | Seo de Urgel - Manresa |
| 34 | 1971 | GENTY Jean-Claude | 2:07 | Stage 3 | Manresa - Puigcerdá |
| 35 | 1962 | JIMÉNEZ Julio | 2:04 | Stage 5 | Manresa - Argentona |
| 36 | 1950 | SERRA José | 2:03 | Stage 9 | Terrassa - Barcelona |
| 37 | 2003 | KINTANA Aitor | 2:00 | Stage 3 | La Pobla De Mafumet - Andorra (Cortals D'encamp) |
| 38 | 1953 | BOTELLA Salvador | 1:58 | Stage 3 | Granollers - Andorra la Vella |
| 39 | 1959 | COLETTE Claude | 1:55 | Stage 5b | Vilanova de Bellpuig - Manresa |
| 40 | 1968 | GABICA Francisco | 1:55 | Stage 7 | Roses - Caldes d'Estrac |
| 41 | 1970 | SOHET Marc | 1:54 | Stage 8 | Mataró - Calafell |
| 42 | 1960 | GÓMEZ Antonio | 1:50 | Stage 3b | Falset - Tortosa |
| 43 | 1945 | CARRETERO Vicente | 1:48 | Stage 2 | Manresa - Reus |
| 44 | 1987 | BAGOT Jean-Claude | 1:47 | Stage 8b | Banyoles - Playa de Aro |
| 45 | 1947 | GUAL Miguel | 1:46 | Stage 3 | Figueres - Berga |
| 46 | 1964 | MORALES Roberto | 1:43 | Stage 2 | Calella - Lloret de Mar |
| 47 | 1945 | ZIMMERMANN Robert | 1:34 | Stage 11a (ITT) | Girona - Lloret de Mar |
| 48 | 1974 | HUELAMO Jaime | 1:31 | Stage 5 | Playa de Aro - Campdevánol |
| 49 | 1956 | ITURAT Vicente | 1:30 | Stage 5 | Lérida - Vinaroz |
| 50 | 2024 | POGAČAR Tadej | 1:23 | Stage 2 | Mataró - Vallter 2000 |
| 51 | 2014 | WESTRA Lieuwe | 1:22 | Stage 7 | Barcelona - Barcelona |
| 52 | 2001 | DE PAOLI Daniele | 1:20 | Stage 7 | Taull - Els Cortals D'Encamps |
| 53 | 1948 | RODRÍGUEZ Emilio | 1:20 | Stage 4 | Vic - Andorra la Vella |
| 54 | 1957 | COMPANY Gabriel | 1:19 | Stage 5 | Tortosa - Lérida |
| 55 | 1989 | ALONSO Marino | 1:17 | Stage 4 | Tárrega - Manresa |
| 56 | 1951 | VOLPI Primo | 1:17 | Stage 1 | Sant Esteve Sesrovires - Granollers |
| 57 | 1948 | LANGARICA Dalmacio | 1:15 | Stage 9 | Manresa - Barcelona |
| 58 | 1956 | ESCOLÀ Juan | 1:09 | Stage 3 | Igualada - Puigcerda |
| 59 | 1996 | ZÜLLE Alex | 1:09 | Stage 3 (ITT) | Martinet - Les |
| 60 | 1982 | OCAÑA Ángel | 1:09 | Stage 4 | Lleida - Viella |
| 61 | 1959 | DANTE Giuseppe | 1:08 | Stage 4 | Tortosa - Lérida |
| 62 | 2016 | DE GENDT Thomas | 1:08 | Stage 4 | Bagà - Port Ainé |
| 63 | 1981 | DEMIERRE Serge | 1:08 | Stage 7a | Vilafranca de Panades - Vilafranca de Penedes |
| 64 | 1950 | LANGARICA Dalmacio | 1:07 | Stage 8 | Figueres - Terrassa |
| 65 | 1974 | LÓPEZ Vicente | 1:04 | Stage 7a | Orgañá - Cardona |
| 66 | 1989 | EMONDS Nico | 1:03 | Stage 7 | Cerdañola - Playa de Aro |
| 67 | 1951 | LOROÑO Jesús | 1:02 | Stage 7 | Tortosa - Amposta |
| 68 | 1979 | VAN IMPE Lucien | 1:02 | Stage 7a (ITT) | Playa de Aro - Tossa |
| 69 | 1977 | MARTINEZ Enrique | 1:02 | Stage 6 | Playa de Aro - La Garriga |
| 70 | 2000 | JIMÉNEZ José María | 0:59 | Stage 7 | Prades - El Cortals |
| 71 | 1949 | MENON Angelo | 0:59 | Stage 9 | Tortosa - Villanova y Geltrú |
| 72 | 2024 | POGAČAR Tadej | 0:57 | Stage 6 | Berga - Queralt |
| 73 | 1968 | EREÑOZAGA Gabino | 0:56 | Stage 5 | Tremp - Vic |
| 74 | 1977 | MAERTENS Freddy | 0:55 | Stage 7a (ITT) | La Garriga - Granollers |
| 75 | 1981 | BELDA Vicente | 0:54 | Stage 3 | Barcelona - Arbucias |
| 76 | 1955 | BAHAMONTES Federico | 0:54 | Stage 11 | Vilanova i la Geltrú - Barcelona |
| 77 | 1959 | KARMANY Antonio | 0:52 | Stage 7 | Palafrugell - Berga |
| 78 | 1962 | SÁNCHEZ CAMERO Juan | 0:52 | Stage 6 | Argentona - Banolas |
| 79 | 2006 | CASTAÑO Carlos | 0:52 | Stage 4 | Perafort - Vallnord/Sector Arcalís |
| 80 | 1986 | KELLY Sean | 0:52 | Stage 7 (ITT) | Alghero - Alghero |
| 81 | 2003 | PECHARROMÁN José Antonio | 0:52 | Stage 6 (ITT) | Molins De Rei - Vallvidrera (Barcelona) |
| 82 | 2019 | FORMOLO Davide | 0:51 | Stage 7 | Barcelona - Barcelona |
| 83 | 1955 | BOTELLA Salvador | 0:49 | Stage 9 | Reus - Vilanova i la Geltrú |
| 84 | 2024 | POGAČAR Tadej | 0:48 | Stage 3 | Sant Joan de les Abadesses - Port Ainé |
| 85 | 1962 | GARCÍA Ginés | 0:47 | Stage 3a | Zaragoza - Binefar |
| 86 | 1972 | GIMONDI Felice | 0:47 | Stage 5b (ITT) | Badalona - Badalona |
| 87 | 1967 | ANQUETIL Jacques | 0:46 | Stage 7b (ITT) | Figueres - Estarlit |
| 88 | 1997 | BOARDMAN Chris | 0:46 | Stage 5 (ITT) | Vic - Vic |
| 89 | 1974 | THÉVENET Bernard | 0:44 | Stage 7b (ITT) | Cardona - Manresa |
| 90 | 1971 | OCAÑA Luis | 0:43 | Stage 5b (ITT) | Sabadell - Sabadell |
| 91 | 1976 | BERTOGLIO Fausto | 0:42 | Stage 7a (ITT) | Sant Celoni - argentona |
| 92 | 1957 | MOSTAJO Santiago | 0:42 | Stage 7 | Puigcerda - Granollers |
| 93 | 2012 | ALBASINI Michael | 0:42 | Stage 1 | Calella - Calella |
| 94 | 1963 | URIONA Valentín | 0:42 | Stage 7b (ITT) | Salomó - Reus |
| 95 | 1951 | RODRÍGUEZ Manuel | 0:40 | Stage 9 | Valls - Les Escaldes |
| 96 | 1962 | PÉREZ FRANCÉS José | 0:40 | Stage 7 (ITT) | Banolas - Palafrugell |
| 97 | 1952 | GROSSO Adolfo | 0:39 | Stage 7b (ITT) | Tona - Granollers |
| 98 | 1950 | GELABERT Antonio | 0:39 | Stage 7 | Manresa - Figueres |
| 99 | 2021 | KÄMNA Lennard | 0:39 | Stage 5 | La Pobla de Segur - Manresa |
| 100 | 1968 | MERCKX Eddy | 0:38 | Stage 6b (ITT) | Figueres - Roses |