| 1 | Horner Chris | 41y + 315d | 2013 | Stage 10 - Torredelcampo › Güéjar Sierra. Alto de Hazallanas |
| 2 | Valverde Alejandro | 39y + 126d | 2019 | Stage 7 - Onda › Mas de la Costa |
| 3 | Martín Manuel | 37y + 334d | 1969 | Stage 10 - Reus › Barcelona |
| 4 | Gilbert Philippe | 37y + 68d | 2019 | Stage 17 - Aranda de Duero › Guadalajara |
| 5 | Zabel Erik | 37y + 62d | 2007 | Stage 7 - Calahorra › Zaragoza |
| 6 | De Vlaeminck Roger | 36y + 245d | 1984 | Stage 8 - Cardona › Zaragoza |
| 7 | Petacchi Alessandro | 36y + 243d | 2010 | Stage 7 - Murcia › Orihuela |
| 8 | Lauritzen Dag-Otto | 36y + 240d | 1993 | Stage 15 - Santo Domingo de la Calzada › Santander |
| 9 | Moncoutié David | 36y + 123d | 2011 | Stage 11 - Verín › Estación de Montaña Manzaneda |
| 10 | Rodríguez Joaquim | 36y + 117d | 2015 | Stage 15 - Comillas › Sotres. Cabrales |
| 11 | Laiseka Roberto | 36y + 81d | 2005 | Stage 11 - Andorra › Cerler |
| 12 | Berrendero Julián | 36y + 66d | 1948 | Stage 1 (ITT) |
| 13 | Piepoli Leonardo | 35y + 345d | 2007 | Stage 9 - Huesca › Estación de esquí Cerler |
| 14 | Lagutin Sergey | 35y + 225d | 2016 | Stage 8 - Villalpando › La Camperona. Valle de Sabero |
| 15 | Lastras Pablo | 35y + 214d | 2011 | Stage 3 - Petrer › Totana |
| 16 | Plaza Rubén | 35y + 195d | 2015 | Stage 20 - San Lorenzo de El Escorial › Cercedilla |
| 17 | Rominger Tony | 35y + 184d | 1996 | Stage 21 (ITT) - Segovia › Segovia |
| 18 | Cipollini Mario | 35y + 175d | 2002 | Stage 7 - Jaén › Málaga |
| 19 | Schleck Fränk | 35y + 144d | 2015 | Stage 16 - Luarca › Ermita de Alba. Quiros |
| 20 | Cardona Salvador | 35y + 121d | 1936 | Stage 9 - Valencia › Tarragona |
| 21 | Arrieta José Luis | 35y + 92d | 2006 | Stage 19 - Jaén › Ciudad Real |
| 22 | Leipheimer Levi | 34y + 332d | 2008 | Stage 20 (ITT) - La Granja de San Ildefonso › Alto de Navacerrada |
| 23 | Mosquera Ezequiel | 34y + 304d | 2010 | Stage 20 - San Martín de Valdeiglesias › Bola del Mundo |
| 24 | Assirelli Nino | 34y + 286d | 1960 | Stage 6 - Zamora › Madrid |
| 25 | Contador Alberto | 34y + 278d | 2017 | Stage 20 - Corvera de Asturias › Alto de l'Angliru |
| 26 | Menchov Denis | 34y + 227d | 2012 | Stage 20 - La Faisanera Golf. Segovia 21 › Bola del Mundo |
| 27 | Bugno Gianni | 34y + 216d | 1998 | Stage 12 - Benasque › Canfranc |
| 28 | Hinault Sébastien | 34y + 211d | 2008 | Stage 10 - Sabiñánigo › Zaragoza |
| 29 | Fuglsang Jakob | 34y + 171d | 2019 | Stage 16 - Pravia › Alto de La Cubilla. Lena |
| 30 | Bettini Paolo | 34y + 164d | 2008 | Stage 12 - Burgos › Suances |
| 31 | Magni Fiorenzo | 34y + 151d | 1955 | Stage 15 |
| 32 | Perurena Domingo | 34y + 151d | 1978 | Stage 19a - Amurrio › San Sebastián |
| 33 | Niemiec Przemysław | 34y + 149d | 2014 | Stage 15 - Oviedo › Lagos de Covadonga |
| 34 | Karstens Gerben | 34y + 116d | 1976 | Stage 12 - Pamplona › Logroño |
| 35 | Yáñez Felipe | 34y + 97d | 1987 | Stage 9 - Zaragoza › Pamplona |
| 36 | Martin Dan | 34y + 64d | 2020 | Stage 3 - Lodosa › La Laguna Negra de Vinuesa |
| 37 | Roscioli Fabio | 34y + 63d | 1999 | Stage 14 - Barcelona › Barcelona |
| 38 | Lameire Marnix | 34y + 53d | 1989 | Stage 1 - La Coruña › La Coruña |
| 39 | Fombellida Alejandro | 34y + 50d | 1947 | Stage 21 - Orense › Astorga |
| 40 | Woods Michael | 34y + 16d | 2020 | Stage 7 - Vitoria-Gasteiz › Villanueva de Valdegovia |
| 41 | McCartney Jason | 34y + 12d | 2007 | Stage 14 - Puerto › Villacarrillo |
| 42 | Montes Antonio | 33y + 332d | 1945 | Stage 6 - Sevilla › Granada |
| 43 | Hesjedal Ryder | 33y + 271d | 2014 | Stage 14 - Santander › La Camperona |
| 44 | Gelabert Antonio | 33y + 230d | 1955 | Stage 3 - Bayona › Pamplona |
| 45 | Ekimov Viatcheslav | 33y + 228d | 1999 | Stage 15 - La Senia › Valencia |
| 46 | Hamilton Tyler | 33y + 195d | 2004 | Stage 8 (ITT) - Almusafes › Almusafes |
| 47 | Lasa Miguel María | 33y + 188d | 1981 | Stage 17 - Torrejón de Ardoz › Segovia |
| 48 | Marczyński Tomasz | 33y + 178d | 2017 | Stage 12 - Motril › Antequera Los Dólmenes |
| 49 | López Vicente | 33y + 162d | 1976 | Stage 15 - Gijón › Cangas de Onís |
| 50 | Hansen Adam | 33y + 124d | 2014 | Stage 19 - Salvaterra de Miño › Cangas de Morrazo |
| 51 | Desmet Armand | 33y + 101d | 1964 | Stage 4b - Barcelona › Barcelona |
| 52 | Pérez Luis | 33y + 96d | 2007 | Stage 18 - Talavera de la Reina › Ávila |
| 53 | Novak Anatole | 33y + 80d | 1970 | Stage 10 - Igualada › Zaragoza |
| 54 | Pollentier Michel | 33y + 70d | 1984 | Stage 6 - Salou › Sant Quirze del Vallès |
| 55 | Baffi Adriano | 33y + 46d | 1995 | Stage 19 - Sabiñánigo › Calatayud |
| 56 | Agostinho Joaquim | 33y + 27d | 1976 | Stage 6 (ITT) - Cartagena › Cartagena |
| 57 | Andrés Francisco Antonio | 33y + 25d | 1946 | Stage 2a (ITT) - Salamanca › Béjar |
| 58 | Vinokourov Alexandre | 32y + 365d | 2006 | Stage 20 (ITT) - Rivas Vaciamadrid › Rivas Vaciamadrid |
| 59 | Henderson Gregory | 32y + 355d | 2009 | Stage 3 - Zutphen › Venlo |
| 60 | Møller Claus Michael | 32y + 355d | 2001 | Stage 15 - Valencia › Alto de Aitana |
| 61 | Pascual Rodríguez Javier | 32y + 314d | 2004 | Stage 18 - Béjar › Ávila |
| 62 | Moser Francesco | 32y + 314d | 1984 | Stage 11 - Burgos › Santander |
| 63 | Braeckeveldt Omer | 32y + 311d | 1950 | Stage 1 - Madrid › Valladolid |
| 64 | Nibali Vincenzo | 32y + 280d | 2017 | Stage 3 - Prades Conflent Canigó › Andorra la Vella |
| 65 | Pino Álvaro | 32y + 266d | 1989 | Stage 17 - Santoña › Lagos de Covadonga |
| 66 | Millar David | 32y + 258d | 2009 | Stage 20 (ITT) - Toledo › Toledo |
| 67 | Iturat Vicente | 32y + 249d | 1961 | Stage 3 - Pamplona › Huesca |
| 68 | Hushovd Thor | 32y + 227d | 2010 | Stage 6 - Caravaca de Cruz › Murcia |
| 69 | Freire Óscar | 32y + 208d | 2008 | Stage 11 - Calahorra › Burgos |
| 70 | Van Impe Lucien | 32y + 201d | 1979 | Stage 15 - Gijón › León |
| 71 | van Heeswijk Max | 32y + 184d | 2005 | Stage 7 - Teruel › Vinaros |
| 72 | Cancellara Fabian | 32y + 170d | 2013 | Stage 11 (ITT) - Tarazona › Tarazona |
| 73 | Elorriaga Javier Francisco | 32y + 156d | 1980 | Stage 15 - Orense › Ponferrada |
| 74 | Zoetemelk Joop | 32y + 150d | 1979 | Stage 8a - Sedaví › Benicasim |
| 75 | Aranzabal Jesus | 32y + 141d | 1972 | Stage 17a - Vitoria › San Sebastián |
| 76 | Manzaneque Jesús | 32y + 129d | 1975 | Stage 19a - Miranda de Ebro › Beasain |
| 77 | Loroño Jesús | 32y + 122d | 1958 | Stage 13a (ITT) - Bilbao › Castro Urdiales |
| 78 | Swerts Roger | 32y + 115d | 1975 | Prologue - Fuengirola › Fuengirola |
| 79 | De Marchi Alessandro | 32y + 109d | 2018 | Stage 11 - Mombuey › Ribeira Sacra. Luintra |
| 80 | Froome Chris | 32y + 108d | 2017 | Stage 16 (ITT) - Circuito de Navarra › Logroño |
| 81 | Ezquerra Federico | 32y + 106d | 1941 | Stage 13 - San Sebastián › Bilbao |
| 82 | Kessiakoff Fredrik | 32y + 104d | 2012 | Stage 11 (ITT) - Cambados › Pontevedra |
| 83 | Otaño Luis | 32y + 101d | 1966 | Stage 10a - Sitges › Barcelona |
| 84 | Grabsch Bert | 32y + 81d | 2007 | Stage 8 (ITT) - D. O. Cariñena › Zaragoza |
| 85 | Bramati Davide | 32y + 79d | 2000 | Stage 16 - Benavente › Salamanca |
| 86 | Kiryienka Vasil | 32y + 76d | 2013 | Stage 18 - Burgos › Peña Cabarga |
| 87 | Stevens Julien | 32y + 75d | 1975 | Stage 19a - Miranda de Ebro › Beasain |
| 88 | Zülle Alex | 32y + 54d | 2000 | Prologue - Málaga › Málaga |
| 89 | Thiétard Louis | 32y + 42d | 1942 | Stage 13 - Luarca › La Coruña |
| 90 | Clarke Simon | 32y + 42d | 2018 | Stage 5 - Granada › Roquetas de Mar |
| 91 | Escuriet Antonio | 32y + 39d | 1941 | Stage 4 - Sevilla › Málaga |
| 92 | Simeoni Filippo | 32y + 38d | 2003 | Stage 19 - Alcobendas › Collado Villalba |
| 93 | Wüst Marcel | 32y + 36d | 1999 | Stage 7 - Salamanca › León |
| 94 | Delgado Pedro | 32y + 25d | 1992 | Stage 14 - Santander › Lagos de Covadonga |
| 95 | Moreno Daniel | 31y + 361d | 2013 | Stage 9 - Antequera › Valdepeñas de Jaén |
| 96 | Gimeno Juan | 31y + 358d | 1945 | Stage 4 (ITT) - Badajoz › Almendralejo |
| 97 | Kelly Sean | 31y + 355d | 1988 | Stage 20 (ITT) - Las Rozas › Collado Villalba |
| 98 | Bennati Daniele | 31y + 347d | 2012 | Stage 18 - Aguilar de Campoo › Valladolid |
| 99 | Vandenbroucke Jean-Luc | 31y + 327d | 1987 | Prologue - Benidorm › Benidorm |
| 100 | Bahamontes Federico | 31y + 306d | 1960 | Stage 13 - Logroño › San Sebastián |