| 1 | 1945 | MONTES Antonio | 23:18 | Stage 6 | Sevilla - Granada |
| 2 | 1950 | MIRÓ Agustín | 17:52 | Stage 4a | Gijón - Santander |
| 3 | 1984 | SUÁREZ Jesús | 16:36 | Stage 18a | Palazuelos de Eresma (Destilerías Dyc) - Torrejón de Ardoz |
| 4 | 1945 | RODRÍGUEZ Delio | 14:53 | Stage 2 | Salamanca - Cáceres |
| 5 | 1981 | LÓPEZ José Luis | 14:50 | Stage 14 | Gironella - Balaguer |
| 6 | 1982 | RECIO José | 11:36 | Stage 13 | Nules - Antella |
| 7 | 1960 | SUÁREZ Antonio | 11:35 | Stage 14 | San Sebastián - Vitoria |
| 8 | 1959 | MAS Gabriel | 11:01 | Stage 6 | Murcia - Alicante |
| 9 | 1972 | BALAGUÉ Luis | 9:32 | Stage 11 | Manresa - Zaragoza |
| 10 | 1991 | MARTÍN Jesús Cruz | 9:24 | Stage 4 | Sevilla - Jaén |
| 11 | 1976 | PINTENS Georges | 9:22 | Stage 8 | Murcia - Almansa |
| 12 | 1956 | AZPURU Benigno | 8:52 | Stage 16 | Bilbao - Vitoria |
| 13 | 1967 | VAN DER VLEUTEN Jos | 8:43 | Stage 14 | Zaragoza - Pamplona |
| 14 | 1983 | HERNÁNDEZ Jesús | 8:38 | Stage 18 | Ávila - Palazuelos de Eresma (Destilerías Dyc) |
| 15 | 1981 | PINO Álvaro | 8:28 | Stage 16 | Calatayud - Torrejón de Ardoz |
| 16 | 1979 | ARGUDO Juan | 8:27 | Stage 5 | Puerto Lumbreras - Murcia |
| 17 | 1946 | BERRENDERO Julián | 7:08 | Stage 21 | Valladolid - Madrid |
| 18 | 1985 | CAMARILLO Angel | 6:57 | Stage 8 | Aguilar de Campoo - Logroño |
| 19 | 1994 | ALONSO Marino | 6:49 | Stage 19 | Ávila - Palazuelos de Eresma (Destilerías Dyc) |
| 20 | 1958 | BAFFI Pierino | 6:42 | Stage 14 | Santander - Gijón |
| 21 | 1972 | FUENTE José Manuel | 6:37 | Stage 12 | Zaragoza - Formigal |
| 22 | 1945 | REBELO João de Jesús | 6:29 | Stage 13 | San Sebastián - Bilbao |
| 23 | 1974 | GARCÍA Manuel Antonio | 6:25 | Stage 19a | Éibar - San Sebastián |
| 24 | 1950 | RUIZ Bernardo | 5:39 | Stage 8b | Tudela - Zaragoza |
| 25 | 1974 | SANTISTEBAN Juan Manuel | 5:33 | Stage 15 | Cangas de Onís - Laredo |
| 26 | 1958 | IZA Fausto | 5:24 | Stage 12 | Vitoria - Bilbao |
| 27 | 1979 | ALFONSEL Bernardo | 5:21 | Stage 14 | Torrelavega - Gijón |
| 28 | 1956 | ASTRUA Giancarlo | 5:18 | Stage 12 | Zaragoza - Bayona |
| 29 | 1977 | ORDIALES Luis Alberto | 5:09 | Stage 17 | Cordovilla - Bilbao |
| 30 | 1957 | SUÁREZ Antonio | 4:47 | Stage 16 | San Sebastián - Bilbao |
| 31 | 1959 | MANZANEQUE Fernando | 4:45 | Stage 17 | Bilbao - Bilbao |
| 32 | 2023 | EVENEPOEL Remco | 4:44 | Stage 18 | Pola de Allande - La Cruz de Linares |
| 33 | 1976 | VALLORI Antonio | 4:43 | Stage 11 | Cambrils - Barcelona |
| 34 | 2024 | O'CONNOR Ben | 4:33 | Stage 6 | Jerez de la Frontera - Yunquera |
| 35 | 1947 | BERTOLUCCI Bruno | 4:25 | Stage 16a | Oviedo - Luarca |
| 36 | 1988 | NAVARRO Francisco | 4:23 | Stage 5 | Badajoz - Béjar |
| 37 | 1961 | COMPANY Gabriel | 4:18 | Stage 16 | Bilbao - Bilbao |
| 38 | 1984 | ROSSEL Daniel | 4:13 | Stage 16 | León - Valladolid |
| 39 | 1987 | RODRIGUEZ José Francisco | 4:12 | Stage 21 | Palazuelos de Eresma (Destilerías Dyc) - Collado Villalba |
| 40 | 1957 | BAENS Roger | 4:02 | Stage 15 | Bayona - San Sebastián |
| 41 | 1950 | DREI Umberto | 4:01 | Stage 15 | Murcia - Lorca |
| 42 | 1950 | SERRA José | 3:59 | Stage 19b | Jerez de la Frontera - Sevilla |
| 43 | 1968 | MARTÍN Manuel | 3:57 | Stage 8 | Benidorm - Almansa |
| 44 | 2013 | RATTO Daniele | 3:53 | Stage 14 | Bagà - Collada de la Gallina |
| 45 | 1970 | VAN DER VLEUTEN Jos | 3:52 | Stage 19a | San Sebastián - Llodio |
| 46 | 1985 | RECIO José | 3:48 | Stage 14 | Valencia - Benidorm |
| 47 | 1987 | ESPARZA Antonio | 3:44 | Stage 15 | La Coruña - Vigo |
| 48 | 1980 | ELORRIAGA Javier Francisco | 3:44 | Stage 15 | Orense - Ponferrada |
| 49 | 1980 | LAMMERTINK Jos | 3:44 | Stage 9 | Logroño - Burgos |
| 50 | 1948 | MESA Senén | 3:36 | Stage 14 | Santander - Gijón |
| 51 | 1980 | RUPÉREZ Faustino | 3:28 | Stage 5 | Sant Quirze del Vallès - Seo de Urgel |
| 52 | 1995 | ZÜLLE Alex | 3:20 | Stage 16 | Tárrega - Pla de Beret |
| 53 | 1995 | JALABERT Laurent | 3:16 | Stage 8 | Salamanca - Ávila |
| 54 | 1965 | MARTÍN Esteban | 3:16 | Stage 11 | Barcelona - Andorra |
| 55 | 1985 | SARRAPIO José Angel | 3:14 | Stage 13 | Andorra - San Quirico de Tarrasa |
| 56 | 1992 | CADENA Julio César | 3:13 | Stage 10 | Luz-Saint-Sauveur - Sabiñánigo |
| 57 | 1950 | CAPÓ Bernardo | 3:05 | Stage 8a (ITT) | Pamplona - Tudela |
| 58 | 1985 | DE WOLF Fons | 3:04 | Stage 9 | Logroño - Balneario de Panticosa |
| 59 | 2013 | GENIEZ Alexandre | 3:03 | Stage 15 | Andorra - Peyragudes |
| 60 | 1990 | EMONDS Nico | 3:00 | Stage 13 | Oviedo - Santander |
| 61 | 1958 | JIMÉNEZ Antonio | 2:58 | Stage 2 | San Sebastián - Pamplona |
| 62 | 2001 | BLANCO Santiago | 2:57 | Stage 10 | Sabadell - La Molina |
| 63 | 1947 | VAN DIJCK Edward | 2:55 | Stage 22 (ITT) | Astorga - León |
| 64 | 1984 | MASCIARELLI Palmiro | 2:55 | Stage 10 | Soria - Burgos |
| 65 | 1965 | POULIDOR Raymond | 2:52 | Stage 4a (ITT) | Mieres - Puerto de Pajares |
| 66 | 1992 | TORRES Roberto | 2:51 | Stage 13 | Burgos - Santander |
| 67 | 1999 | ULLRICH Jan | 2:50 | Stage 20 (ITT) | El Tiemblo - Ávila |
| 68 | 1969 | PINGEON Roger | 2:49 | Stage 12 | Sant Feliú de Guíxols - Moià |
| 69 | 1969 | DÍAZ Mariano | 2:46 | Stage 15 | Zaragoza - Pamplona |
| 70 | 1965 | MARTÍN Manuel | 2:45 | Stage 18 | Vitoria - Bilbao |
| 71 | 2008 | BALLAN Alessandro | 2:42 | Stage 7 | Barbastro - Andorra (Naturlandia-La Rabassa) |
| 72 | 1947 | VAN DIJCK Edward | 2:41 | Stage 16b (ITT) | Luarca - Ribadeo |
| 73 | 1963 | ANQUETIL Jacques | 2:40 | Stage 1b (ITT) | Mieres - Gijón |
| 74 | 1981 | NIEUWDORP Heddy | 2:40 | Stage 5 | Cáceres - Mérida |
| 75 | 1948 | RUÍZ Victorio | 2:37 | Stage 20 | Segovia - Madrid |
| 76 | 1986 | GOMEZ Marc | 2:33 | Stage 1 | Palma de Mallorca - Palma de Mallorca |
| 77 | 1979 | LÓPEZ Ángel | 2:33 | Stage 13 | Haro - Peña Cabarga |
| 78 | 1960 | BAHAMONTES Federico | 2:32 | Stage 13 | Logroño - San Sebastián |
| 79 | 1967 | IBÁÑEZ Ángel | 2:31 | Stage 13 | Lérida - Zaragoza |
| 80 | 1964 | DE WOLF Henri | 2:25 | Stage 10 | San Sebastián - Bilbao |
| 81 | 1970 | ERRANDONEA José María | 2:23 | Stage 18 | Vitoria - San Sebastián |
| 82 | 2009 | CUNEGO Damiano | 2:23 | Stage 14 | Granada - La Pandera |
| 83 | 1998 | ZINTCHENKO Andrei | 2:20 | Stage 13 | Sabiñanigo - Sabiñanigo |
| 84 | 2000 | SIMONI Gilberto | 2:19 | Stage 16 | Oviedo - Alto de l'Angliru |
| 85 | 1956 | DEFILIPPIS Nino | 2:18 | Stage 15 | San Sebastián - Bilbao |
| 86 | 1972 | ARANZABAL Jesús | 2:13 | Stage 17a | Vitoria - San Sebastián |
| 87 | 1964 | SANZ Julio | 2:12 | Stage 7 | Lérida - Jaca |
| 88 | 1948 | MESA Senén | 2:12 | Stage 13 | Bilbao - Santander |
| 89 | 1990 | ESNAULT Patrice | 2:04 | Stage 5 | Almería - Sierra Nevada |
| 90 | 1987 | IBAÑEZ Jesus Ignacio | 2:02 | Stage 6 | Barcelona - Andorra (Grau Roig) |
| 91 | 2012 | PIEDRA Antonio | 2:02 | Stage 15 | La Robla - Lagos de Covadonga |
| 92 | 2002 | GARCÍA ACOSTA José Vicente | 2:02 | Stage 19 | Béjar - Ávila |
| 93 | 1971 | OCAÑA Luis | 2:01 | Stage 12 | Bilbao - Vitoria |
| 94 | 1980 | ESPARZA Manuel | 2:01 | Stage 18 | Valladolid - Los Ángeles de San Rafael |
| 95 | 1956 | LE BER Claude | 1:59 | Stage 13a (ITT) | Bayona - Irún |
| 96 | 1960 | DECABOOTER Arthur | 1:57 | Stage 15 | Vitoria - Santander |
| 97 | 2002 | SMETANINE Serguei | 1:57 | Stage 14 | Santander - Gijón |
| 98 | 1958 | BAFFI Pierino | 1:56 | Stage 3 | Pamplona - Zaragoza |
| 99 | 1978 | HINAULT Bernard | 1:56 | Stage 18 | Bilbao - Amurrio |
| 100 | 1959 | RIVIÈRE Roger | 1:54 | Stage 14 (ITT) | Éibar - Vitoria |