| 1 | 1984 | JUAREZ Isidro | 6:37 | Stage 5 | Villaviciosa - Asturella |
| 2 | 1957 | MASIP Francesco | 5:33 | Stage 3 | Oviedo - Cangas del Narcea |
| 3 | 2006 | SÁNCHEZ Samuel | 5:01 | Stage 3 | Cangas Del Narcea - Gijón |
| 4 | 1955 | BAHAMONTES Federico | 4:44 | Stage 6 | Oviedo - Mieres |
| 5 | 1954 | ALOMAR Francisco | 4:36 | Stage 3 | - |
| 6 | 1954 | ZAMPINI Donato | 3:41 | Stage 2 | - |
| 7 | 1955 | BERTRAN Antonio | 3:24 | Stage 3 | Gijón - Cangas del Narcea |
| 8 | 1953 | VAN GENECHTEN Richard | 2:56 | Stage 7 | Oviedo - Mieres |
| 9 | 1988 | ECHAVE Federico | 2:48 | Stage 4 | Pola de Siero - Pola de Laviana |
| 10 | 1953 | ITURAT Vicente | 2:28 | Stage 6 (ITT) | Gijón - Oviedo |
| 11 | 1954 | BIBILONI Juan | 1:52 | Stage 5 | - |
| 12 | 1990 | DE LAS CUEVAS Armand | 1:50 | Stage 4 | Oviedo - Cangas del Narcea |
| 13 | 1954 | RUIZ Bernardo | 1:48 | Stage 4 (ITT) | - |
| 14 | 2010 | ZABALLA Constantino | 1:36 | Stage 6 | Fuentes Del Narcea - Oviedo |
| 15 | 1997 | FERNÁNDEZ GINÉS Manuel | 1:32 | Stage 5 | Gijón - Alto del Acebo |
| 16 | 1957 | MAS Gabriel | 1:31 | Stage 6 | Sama de Langreo - Gijón |
| 17 | 1953 | GELABERT Antonio | 1:27 | Stage 3 | Luarca - Avilés |
| 18 | 2003 | VALDÉS Ricardo | 1:26 | Stage 3 | Gijón - Avilés |
| 19 | 1953 | BAHAMONTES Federico | 1:07 | Stage 1 | Mieres - Luarca |
| 20 | 2002 | ZINTCHENKO Andrei | 1:05 | Stage 2 | Llanes - Gijon |
| 21 | 1971 | PESARRODONA José | 1:04 | Stage 4 | Oviedo - Panes |
| 22 | 2024 | DEL TORO Isaac | 1:01 | Stage 1 | Cangas del Narcea - Pola de Lena |
| 23 | 1954 | POBLET Miguel | 1:00 | Stage 6 | - |
| 24 | 1957 | BAHAMONTES Federico | 0:59 | Stage 1 | Mieres - Llanes |
| 25 | 2004 | BARREDO Carlos | 0:48 | Stage 3 | Gijón - Avilés |
| 26 | 1957 | MARIGIL René | 0:44 | Stage 5 | Avilés - Sama de Langreo |
| 27 | 2008 | MARCZYŃSKI Tomasz | 0:43 | Stage 5 | Pravia - El Acebo |
| 28 | 2018 | CARAPAZ Richard | 0:42 | Stage 2 | Soto de Ribera - Alto del Acebo |
| 29 | 1957 | MANZANEQUE Fernando | 0:38 | Stage 7 | Gijón - Mieres |
| 30 | 2022 | YATES Simon | 0:37 | Stage 3 | Cangas del Narcea - Oviedo |
| 31 | 1995 | CHIURATO Andrea | 0:36 | Stage 2 | Avilés - Lagos de Covadonga |
| 32 | 1988 | GÖLZ Rolf | 0:31 | Stage 5 | Pola de Laviana - Cangas de Onis |
| 33 | 1957 | FERRAZ Antonio | 0:30 | Stage 4 | Cangas del Narcea - Avilés |
| 34 | 2012 | MARQUE Alejandro Manuel | 0:29 | Stage 1 | Oviedo - Gijon |
| 35 | 2023 | FORTUNATO Lorenzo | 0:27 | Stage 2 | Candás - Cangas del Narcea |
| 36 | 2021 | QUINTANA Nairo | 0:26 | Stage 1 | Oviedo - Pola de Lena |
| 37 | 1995 | INDURÁIN Miguel | 0:26 | Prologue | Oviedo - Alto del Naranco |
| 38 | 2003 | JEKER Fabian | 0:23 | Stage 4 | Cafés Toscaf - Santuario del Acebo |
| 39 | 2001 | DOMÍNGUEZ Juan Carlos | 0:23 | Stage 6b (ITT) | Oviedo - Alto del Naranco |
| 40 | 2017 | ROLDÁN Weimar Alfonso | 0:22 | Stage 1 | Oviedo - Pola de Lena |
| 41 | 2016 | CARTHY Hugh | 0:22 | Stage 1 | Oviedo - Alto del Acebo |
| 42 | 2004 | GONZALEZ Jonathan | 0:20 | Stage 4 | Cafés Toscaf - Santuario del Acebo |
| 43 | 1996 | INDURÁIN Miguel | 0:19 | Prologue | Oviedo - Naranco |
| 44 | 1955 | MARCOCCIA Giuseppe | 0:18 | Stage 5 | Ávila - Oviedo |
| 45 | 2023 | SÁNCHEZ Pelayo | 0:17 | Stage 3 | Cangas del Narcea - Oviedo |
| 46 | 2010 | INTXAUSTI Beñat | 0:17 | Stage 4 (ITT) | Piedras Blancas - Piedras Blancas |
| 47 | 2010 | DUARTE Fabio | 0:16 | Stage 5 | Cafés Toscaf - Alto del Acebo |
| 48 | 2022 | YATES Simon | 0:14 | Stage 1 | Oviedo - Pola de Lena |
| 49 | 2015 | ANTÓN Igor | 0:14 | Stage 1 | Oviedo - Pola de Lena |
| 50 | 2022 | SOSA Iván Ramiro | 0:11 | Stage 2 | Candás - Cangas del Narcea |
| 51 | 2011 | CABEDO Víctor | 0:11 | Stage 5 | Cafes Toscafa - Oviedo |
| 52 | 1971 | SANTISTEBAN Juan Manuel | 0:10 | Stage 5a | Pares - Llanes |
| 53 | 1984 | IBAÑEZ Jesus Ignacio | 0:10 | Stage 6a | Asturella - Alto del Naranco |
| 54 | 2000 | BELOKI Joseba | 0:10 | Stage 5 | Pravia - Alto del Acebo |
| 55 | 2000 | AZEVEDO José Bento | 0:10 | Stage 4 | Gijon - Alto del Viso |
| 56 | 1957 | MASIP Francesco | 0:09 | Stage 2 | Llanes - Oviedo |
| 57 | 2018 | MESTRE Ricardo | 0:09 | Stage 3 | Cangas del Narcea - Oviedo |
| 58 | 1971 | AJA Gonzalo | 0:09 | Stage 5b | Llanes - Llanes |
| 59 | 1996 | GONZÁLEZ DE GALDEANO Álvaro | 0:09 | Stage 4 | Villaviciosa - Gijón |
| 60 | 2011 | MORENO Javier | 0:08 | Stage 4 | Luarca - Santuario del Acebo |
| 61 | 2007 | GARCÍA Rodrigo | 0:08 | Stage 4 | Cangas del Narcea - Gijón |
| 62 | 2001 | BONCIUCOV Igor | 0:08 | Stage 6a | Cangas de Narcea - Oviedo |
| 63 | 2017 | ALARCÓN Raúl | 0:07 | Stage 3 | Cangas del Narcea - Oviedo (Uría) |
| 64 | 2009 | MANCEBO Francisco | 0:07 | Stage 5 | Cafés Toscaf, Peñaullán - Alto del Acebo |
| 65 | 2009 | GUERRA Héctor | 0:07 | Stage 4 (ITT) | Castrillon - Castrillon |
| 66 | 2008 | SÁNCHEZ Samuel | 0:07 | Stage 3 (ITT) | Nueva - Llanes |
| 67 | 2006 | PLAZA Rubén | 0:07 | Stage 5 | Llanes - Oviedo |
| 68 | 2012 | IZAGIRRE Ion | 0:06 | Stage 2b (ITT) | Piedras Blancas - Piedras Blancas |
| 69 | 2000 | LÓPEZ DE MUNAIN Alberto | 0:06 | Prologue | Oviedo - Alto del Naranco |
| 70 | 1997 | OLANO Abraham | 0:06 | Prologue | Avilés - Avilés |
| 71 | 2005 | GALPARSORO Dionisio | 0:05 | Stage 4 | Cangas - Narcea |
| 72 | 1990 | ALCALÁ Raúl | 0:05 | Prologue | Aviles - Aviles |
| 73 | 1990 | ALCALÁ Raúl | 0:05 | Prologue | Aviles - Aviles |
| 74 | 2001 | LÓPEZ DE MUNAIN Alberto | 0:05 | Stage 5 | Pravia - El Acebo |
| 75 | 2023 | HOWSON Damien | 0:04 | Stage 1 | Oviedo - Pola de Lena |
| 76 | 1971 | GONZÁLEZ José Antonio | 0:04 | Prologue | Gijón - Gijón |
| 77 | 2019 | PINTO Edgar | 0:04 | Stage 3 | Cangas del Narcea - Oviedo |
| 78 | 2013 | TXURRUKA Amets | 0:04 | Stage 1 | Oviedo - Pola de Lena |
| 79 | 2011 | SCHUMACHER Stefan | 0:04 | Stage 3 (ITT) | Piedras Blancas - Piedras Blancas |
| 80 | 2025 | SOLER Marc | 0:03 | Stage 4 | Navia - Oviedo |
| 81 | 2004 | MARTÍN PERDIGUERO Miguel Ángel | 0:03 | Stage 5 | Cangas del Narcea - Oviedo |
| 82 | 1988 | NEVENS Jan | 0:03 | Stage 6a | Cangas de Onis - Alto del Naranco |
| 83 | 2006 | SEVILLA Óscar | 0:02 | Stage 2 | Cafés Toscaf - Alto Del Acebo |
| 84 | 2004 | HERRERO David | 0:02 | Stage 2 | Llanes - Gijón |
| 85 | 1971 | CASTELLO Eduardo | 0:02 | Stage 2 | Cangas de Narcea - Sama de Langreo |
| 86 | 2021 | LATOUR Pierre | 0:02 | Stage 3 | Cangas del Narcea - Alto del Naranco |
| 87 | 2005 | KHALILOV Mikhaylo | 0:02 | Stage 5 | Gijon - Oviedo |
| 88 | 2003 | MAESTRE José Manuel | 0:02 | Stage 1 | Oviedo - Llanes |
| 89 | 2006 | ARTETXE Mikel | 0:02 | Stage 4 | Gijón - Llanes |
| 90 | 2008 | URTASUN Pablo | 0:02 | Stage 6 | Cangas del Narcea - Oviedo |
| 91 | 2012 | DI GRÉGORIO Rémy | 0:02 | Stage 3 | Lugones - Alto del Naranco |
| 92 | 2002 | ARRIETA José Luis | 0:01 | Stage 1 | Oviedo - Llanes |
| 93 | 2025 | GARCÍA CORTINA Iván | 0:01 | Stage 2 | Benia de Onís - Pola de Lena |
| 94 | 1984 | CORREDOR Edgar | 0:00 | Stage 4 | Pola de Laviana - Villaviciosa |
| 95 | 2012 | HERRADA Jesús | 0:00 | Stage 2a | Teverga - Avilés |
| 96 | 1984 | IGLESIAS Miguel Ángel | 0:00 | Stage 6b | Oviedo - Oviedo |
| 97 | 2011 | SCHUMACHER Stefan | 0:00 | Stage 1 | Oviedo - Gijon |
| 98 | 2010 | SOBRINO Joaquin | 0:00 | Stage 3 | Gijón - Avilés |
| 99 | 2011 | ZABALLA Constantino | 0:00 | Stage 6 | Tartiere Auto - Alto del Naranco |
| 100 | 1984 | DIETZEN Reimund | 0:00 | Stage 1 | Gijon - Gijon |