| 1 | 1965 | | Vuelta a España | Stage 16 (ITT) | 3 |
| 2 | 1960 | | Vuelta a España | Stage 17b (ITT) | 4 |
| 3 | 1958 | | Vuelta a España | Stage 13a (ITT) | 7 |
| 4 | 1960 | | Barcelona - Madrid | Stage 4 (ITT) | 2 |
| 5 | 1961 | | Vuelta a España | Stage 12 (ITT) | 8 |
| 6 | 1963 | | Vuelta a España | Stage 1b (ITT) | 9 |
| 7 | 1960 | | National Championships Spain - Road Race | 3 |
| 8 | 1964 | | Volta Ciclista a Catalunya | Stage 3b (ITT) | 6 |
| 9 | 1964 | | Vuelta a España | Stage 15 (ITT) | 10 |
| 10 | 1958 | | Vuelta a Levante | Stage 5a (ITT) | 4 |
| 11 | 1960 | | Vuelta a Levante | Stage 4a (ITT) | 4 |
| 12 | 1962 | | Vuelta a España | Stage 15 (ITT) | 11 |
| 13 | 1963 | | Vuelta a España | Stage 12b (ITT) | 11 |
| 14 | 1959 | | Volta Ciclista a Catalunya | Stage 5a (ITT) | 7 |
| 15 | 1961 | | National Championships Spain - Road Race | 4 |
| 16 | 1961 | | Madrid - Barcelona | Stage 6b (ITT) | 7 |
| 17 | 1964 | | Vuelta a España | Stage 1b (ITT) | 14 |
| 18 | 1967 | | Vuelta a España | Stage 15b (ITT) | 14 |
| 19 | 1958 | | Tour de France | Stage 8 (ITT) | 39 |
| 20 | 1958 | | Tour de France | Stage 18 (ITT) | 26 |
| 21 | 1958 | | Tour de France | Stage 23 (ITT) | 21 |
| 22 | 1959 | | Vuelta a España | Stage 14 (ITT) | 18 |
| 23 | 1959 | | National Championships Spain - Road Race | 21 |
| 24 | 1959 | | Tour de France | Stage 6 (ITT) | 64 |
| 25 | 1959 | | Tour de France | Stage 15 (ITT) | 17 |
| 26 | 1959 | | Tour de France | Stage 21 (ITT) | 17 |
| 27 | 1960 | | Tour de France | Stage 1b (ITT) | 65 |
| 28 | 1960 | | Tour de France | Stage 19 (ITT) | 41 |
| 29 | 1961 | | Tour de France | Stage 1b (ITT) | 40 |
| 30 | 1961 | | Tour de France | Stage 19 (ITT) | 16 |
| 31 | 1963 | | Tour de France | Stage 6b (ITT) | 31 |
| 32 | 1963 | | Tour de France | Stage 19 (ITT) | 30 |
| 33 | 1964 | | Tour de France | Stage 10b (ITT) | 68 |
| 34 | 1964 | | Tour de France | Stage 17 (ITT) | 16 |
| 35 | 1964 | | Tour de France | Stage 22b (ITT) | 42 |
| 36 | 1965 | | Vuelta a España | Stage 4a (ITT) | 17 |
| 37 | 1965 | | Tour de France | Stage 5b (ITT) | 68 |
| 38 | 1965 | | Tour de France | Stage 18 (ITT) | 41 |
| 39 | 1965 | | Tour de France | Stage 22 (ITT) | 72 |
| 40 | 1967 | | Vuelta a España | Stage 1b (ITT) | 50 |
| 41 | 1967 | | Vuelta a España | Stage 17 (ITT) | 55 |
| 42 | 1967 | | Tour de France | Prologue | 101 |
| 43 | 1967 | | Tour de France | Stage 22b (ITT) | 34 |