| 1 | 1970 | | Vuelta Ciclista al País Vasco | Stage 3b (ITT) | 1 |
| 2 | 1966 | | Critérium du Dauphiné Libéré | Stage 7b (ITT) | 2 |
| 3 | 1966 | | Vuelta a España | Stage 15a (ITT) | 4 |
| 4 | 1967 | | Vuelta a España | Stage 15b (ITT) | 4 |
| 5 | 1968 | | Baden-Baden | 7 |
| 6 | 1965 | | Volta Ciclista a Catalunya | Stage 1 (ITT) | 3 |
| 7 | 1965 | | Vuelta a España | Stage 4a (ITT) | 6 |
| 8 | 1964 | | Eibarko Bizikleta | Stage 4 | 2 |
| 9 | 1965 | | Vuelta a España | Stage 16 (ITT) | 7 |
| 10 | 1965 | | Volta Ciclista a Catalunya | Stage 6b (ITT) | 5 |
| 11 | 1966 | | Tour de France | Stage 22b (ITT) | 10 |
| 12 | 1966 | | National Championships Spain - Road Race | 2 |
| 13 | 1967 | | National Championships Spain - Road Race | 2 |
| 14 | 1967 | | Giro d'Italia | Stage 16 (ITT) | 9 |
| 15 | 1969 | | Vuelta a España | Stage 16 (ITT) | 10 |
| 16 | 1969 | | Vuelta Ciclista a La Rioja | Stage 3a (ITT) | 6 |
| 17 | 1965 | | Tour de France | Stage 22 (ITT) | 15 |
| 18 | 1963 | | Vuelta a España | Stage 1b (ITT) | 25 |
| 19 | 1963 | | Vuelta a España | Stage 12b (ITT) | 28 |
| 20 | 1964 | | Vuelta a España | Stage 1b (ITT) | 38 |
| 21 | 1964 | | Vuelta a España | Stage 15 (ITT) | 21 |
| 22 | 1964 | | Volta Ciclista a Catalunya | Stage 3b (ITT) | 18 |
| 23 | 1964 | | Volta Ciclista a Catalunya | Stage 7b (ITT) | 18 |
| 24 | 1965 | | Tour de France | Stage 5b (ITT) | 85 |
| 25 | 1965 | | Tour de France | Stage 18 (ITT) | 32 |
| 26 | 1965 | | Volta Ciclista a Catalunya | Stage 5a (ITT) | 47 |
| 27 | 1966 | | Vuelta a España | Stage 1b (ITT) | 32 |
| 28 | 1966 | | Tour de France | Stage 14b (ITT) | 16 |
| 29 | 1966 | | Volta Ciclista a Catalunya | Stage 6b (ITT) | 13 |
| 30 | 1967 | | Vuelta a España | Stage 1b (ITT) | 19 |
| 31 | 1967 | | Vuelta a España | Stage 17 (ITT) | 39 |
| 32 | 1968 | | Tour de France | Prologue | 83 |
| 33 | 1968 | | Tour de France | Stage 22b (ITT) | 20 |
| 34 | 1968 | | National Championships Spain - Road Race | 13 |
| 35 | 1969 | | Vuelta a España | Stage 1a (ITT) | 32 |
| 36 | 1969 | | Vuelta a España | Stage 14b (ITT) | 17 |
| 37 | 1969 | | Vuelta a España | Stage 18b (ITT) | 30 |
| 38 | 1970 | | Vuelta a España | Prologue | 92 |
| 39 | 1970 | | Vuelta a España | Stage 19b (ITT) | 27 |