| 1 | 1966-09-18 | Volta Ciclista a Catalunya | General classification | | | 18 | | | 27 |
| 2 | 1965-05-16 | Vuelta a España | General classification | | | 34 | | | 27 |
| 3 | 1965-05-16 | Vuelta a España | Stage 18 | | | 34 | | | 41 |
| 4 | 1965-05-15 | Vuelta a España | Stage 17 | | | 38 | | | 8 |
| 5 | 1965-05-14 | Vuelta a España | Stage 16 (ITT) | | | 38 | | | 53 |
| 6 | 1965-05-13 | Vuelta a España | Stage 15 | | | 49 | | | 16 |
| 7 | 1965-05-12 | Vuelta a España | Stage 14 | | | 13 | | | 8 |
| 8 | 1965-05-11 | Vuelta a España | Stage 13 | | | 54 | | | 15 |
| 9 | 1965-05-10 | Vuelta a España | Stage 12 | | | 63 | | | 50 |
| 10 | 1965-05-09 | Vuelta a España | Stage 11 | | | 24 | | | 5 |
| 11 | 1965-05-08 | Vuelta a España | Stage 10a | | | 58 | | | 30 |
| 12 | 1965-05-08 | Vuelta a España | Stage 10b | | | 1 | | | 10 |
| 13 | 1965-05-07 | Vuelta a España | Stage 9 | | | 67 | | | 7 |
| 14 | 1965-05-06 | Vuelta a España | Stage 8 | | | 62 | | | 21 |
| 15 | 1965-05-05 | Vuelta a España | Stage 7 | | | 63 | | | 6 |
| 16 | 1965-05-04 | Vuelta a España | Stage 6 | | | 76 | | | 65 |
| 17 | 1965-05-03 | Vuelta a España | Stage 5 | | | 28 | | | 56 |
| 18 | 1965-05-02 | Vuelta a España | Stage 4a (ITT) | | | 10 | | | 36 |
| 19 | 1965-05-02 | Vuelta a España | Stage 4b | | | 66 | | | 15 |
| 20 | 1965-05-01 | Vuelta a España | Stage 3 | | | 52 | | | 13 |
| 21 | 1965-04-30 | Vuelta a España | Stage 2 | | | 64 | | | 65 |
| 22 | 1965-04-29 | Vuelta a España | Stage 1 | | | 57 | | | 48 |
| 23 | 1964-08-23 | National Championships Spain - Road Race | | | 1 | | | 8 |
| 24 | 1964-07-14 | Tour de France | General classification | | | 7 | | | 45 |
| 25 | 1964-07-14 | Tour de France | Stage 22b (ITT) | | | 22 | | | 79 |
| 26 | 1964-07-14 | Tour de France | Stage 22a | | | 78 | | | 62 |
| 27 | 1964-07-13 | Tour de France | Stage 21 | | | 80 | | | 22 |
| 28 | 1964-07-12 | Tour de France | Stage 20 | | | 1 | | | 71 |
| 29 | 1964-07-11 | Tour de France | Stage 19 | | | 77 | | | 5 |
| 30 | 1964-07-10 | Tour de France | Stage 18 | | | 78 | | | 41 |
| 31 | 1964-07-09 | Tour de France | Stage 17 (ITT) | | | 39 | | | 74 |
| 32 | 1964-07-08 | Tour de France | Stage 16 | | | 12 | | | 41 |
| 33 | 1964-07-07 | Tour de France | Stage 15 | | | 16 | | | 20 |
| 34 | 1964-07-06 | Tour de France | Stage 14 | | | 15 | | | 60 |
| 35 | 1964-07-04 | Tour de France | Stage 13 | | | 1 | | | 3 |
| 36 | 1964-07-03 | Tour de France | Stage 12 | | | 48 | | | 9 |
| 37 | 1964-07-02 | Tour de France | Stage 11 | | | 78 | | | 19 |
| 38 | 1964-07-01 | Tour de France | Stage 10b (ITT) | | | 85 | | | 90 |
| 39 | 1964-07-01 | Tour de France | Stage 10a | | | 92 | | | 68 |
| 40 | 1964-06-30 | Tour de France | Stage 9 | | | 31 | | | 46 |
| 41 | 1964-06-29 | Tour de France | Stage 8 | | | 11 | | | 68 |
| 42 | 1964-06-28 | Tour de France | Stage 7 | | | 81 | | | 21 |
| 43 | 1964-06-27 | Tour de France | Stage 6 | | | 81 | | | 13 |
| 44 | 1964-06-26 | Tour de France | Stage 5 | | | 102 | | | 36 |
| 45 | 1964-06-25 | Tour de France | Stage 4 | | | 106 | | | 63 |
| 46 | 1964-06-24 | Tour de France | Stage 3a | | | 85 | | | 54 |
| 47 | 1964-06-23 | Tour de France | Stage 2 | | | 127 | | | 22 |
| 48 | 1964-06-22 | Tour de France | Stage 1 | | | 52 | | | 16 |
| 49 | 1964-03-10 | Barcelona - Andorra | | | 2 | | | 7 |
| 50 | 1964-03-01 | Vuelta a Levante | General classification | | | 25 | | | 16 |
| 51 | 1963-07-21 | National Championships Spain - Road Race | | | 8 | | | DNF |
| 52 | 1963-06-11 | Vuelta Ciclista a La Rioja | General classification | | | 14 | | | 4 |
| 53 | 1963-05-15 | Vuelta a España | General classification | | | 23 | | | 31 |
| 54 | 1963-05-15 | Vuelta a España | Stage 15 | | | 48 | | | 13 |
| 55 | 1963-05-14 | Vuelta a España | Stage 14 | | | 47 | | | 18 |
| 56 | 1963-05-13 | Vuelta a España | Stage 13 | | | 18 | | | 18 |
| 57 | 1963-05-12 | Vuelta a España | Stage 12b (ITT) | | | 37 | | | 51 |
| 58 | 1963-05-12 | Vuelta a España | Stage 12a | | | 59 | | | 4 |
| 59 | 1963-05-11 | Vuelta a España | Stage 11 | | | 63 | | | 64 |
| 60 | 1963-05-10 | Vuelta a España | Stage 10 | | | 57 | | | 58 |
| 61 | 1963-05-09 | Vuelta a España | Stage 9 | | | 70 | | | 4 |
| 62 | 1963-05-08 | Vuelta a España | Stage 8 | | | 28 | | | 2 |
| 63 | 1963-05-07 | Vuelta a España | Stage 7 | | | 29 | | | 10 |
| 64 | 1963-05-06 | Vuelta a España | Stage 6 | | | 19 | | | 39 |
| 65 | 1963-05-05 | Vuelta a España | Stage 5 | | | 11 | | | 36 |
| 66 | 1963-05-04 | Vuelta a España | Stage 4 | | | 65 | | | 4 |
| 67 | 1963-05-03 | Vuelta a España | Stage 3 | | | 43 | | | 47 |
| 68 | 1963-05-02 | Vuelta a España | Stage 2 | | | 59 | | | 1 |
| 69 | 1963-05-01 | Vuelta a España | Stage 1b (ITT) | | | 45 | | | 71 |
| 70 | 1963-05-01 | Vuelta a España | Stage 1a | | | 3 | | | 22 |
| 71 | 1963-04-21 | Mont Faron | | | 5 | | | 9 |
| 72 | 1963-03-15 | Trofeo Jaumendreu | | | 9 | | | 8 |
| 73 | 1962-09-16 | Volta Ciclista a Catalunya | General classification | | | 28 | | | 19 |
| 74 | 1962-09-11 | Volta Ciclista a Catalunya | Stage 3a | | | 2 | | | 4 |
| 75 | 1962-08-05 | National Championships Spain - Road Race | | | DNF | | | 15 |
| 76 | 1962-05-13 | Vuelta a España | General classification | | | 46 | | | 22 |
| 77 | 1962-05-13 | Vuelta a España | Stage 17 | | | 24 | | | 1 |
| 78 | 1962-05-12 | Vuelta a España | Stage 16 | | | 43 | | | 5 |
| 79 | 1962-05-11 | Vuelta a España | Stage 15 (ITT) | | | 38 | | | 42 |
| 80 | 1962-05-10 | Vuelta a España | Stage 14 | | | 41 | | | 8 |
| 81 | 1962-05-09 | Vuelta a España | Stage 13 | | | 60 | | | 11 |
| 82 | 1962-05-08 | Vuelta a España | Stage 12 | | | 62 | | | 6 |
| 83 | 1962-05-07 | Vuelta a España | Stage 11 | | | 62 | | | 29 |
| 84 | 1962-05-06 | Vuelta a España | Stage 10 | | | 30 | | | 12 |
| 85 | 1962-05-05 | Vuelta a España | Stage 9 | | | 66 | | | 30 |
| 86 | 1962-05-04 | Vuelta a España | Stage 8 | | | 68 | | | 5 |
| 87 | 1962-05-03 | Vuelta a España | Stage 7 | | | 71 | | | 12 |
| 88 | 1962-05-02 | Vuelta a España | Stage 6 | | | 71 | | | 10 |
| 89 | 1962-04-30 | Vuelta a España | Stage 4 | | | 78 | | | 7 |
| 90 | 1962-04-29 | Vuelta a España | Stage 3 | | | 80 | | | 58 |
| 91 | 1962-04-28 | Vuelta a España | Stage 2 | | | 81 | | | 51 |
| 92 | 1962-04-27 | Vuelta a España | Stage 1 | | | 7 | | | 7 |
| 93 | 1962-03-25 | Subida a Urkiola | | | 1 | | | 9 |
| 94 | 1961-08-24 | GP Ayutamiento de Bilbao | | | 5 | | | 22 |
| 95 | 1961-04-29 | Vuelta a España | Stage 4 | | | 64 | | | DNF |
| 96 | 1961-04-28 | Vuelta a España | Stage 3 | | | 38 | | | 36 |
| 97 | 1961-04-27 | Vuelta a España | Stage 2 | | | 20 | | | 61 |
| 98 | 1961-04-26 | Vuelta a España | Stage 1b | | | 47 | | | 14 |
| 99 | 1961-03-12 | Vuelta a Levante | General classification | | | 40 | | | 12 |
| 100 | 1960-09-23 | Vuelta Ciclista a La Rioja | General classification | | | 21 | | | 15 |
| 101 | 1960-09-11 | Volta Ciclista a Catalunya | General classification | | | 11 | | | 16 |
| 102 | 1960-04-16 | Eibarko Bizikleta | Stage 1 (ITT) | | | 3 | | | 4 |
| | | | 39 | | | 61 | |