| 1 | 2013-09-04 | Vuelta a España | Stage 11 (ITT) | | | 13 | | | 89 | | 38.8 | |
| 2 | 2013-06-16 | Tour de Suisse | Stage 9 (ITT) | | | 37 | | | OTL | | 26.8 | |
| 3 | 2013-06-08 | Tour de Suisse | Stage 1 (ITT) | | | 120 | | | 22 | | 8.1 | |
| 4 | 2012-06-30 | Tour de France | Prologue | | | 74 | | | 67 | | 6.4 | |
| 5 | 2012-06-22 | National Championships Spain ME - ITT | | | 1 | | | 5 | | 42.3 | |
| 6 | 2012-03-11 | Paris - Nice | Stage 8 (ITT) | | | 53 | | | 60 | | 9.6 | |
| 7 | 2012-03-04 | Paris - Nice | Stage 1 (ITT) | | | 40 | | | 17 | | 9.4 | |
| 8 | 2011-07-23 | Tour de France | Stage 20 (ITT) | | | 69 | | | 114 | | 42.5 | |
| 9 | 2011-06-27 | National Championships Spain ME - ITT | | | 1 | | | 3 | | 44.5 | |
| 10 | 2011-03-11 | Paris - Nice | Stage 6 (ITT) | | | 14 | | | 55 | | 27 | |
| 11 | 2010-09-30 | World Championships ME - ITT | | | 7 | | | 17 | | 45.4 | |
| 12 | 2010-07-24 | Tour de France | Stage 19 (ITT) | | | 76 | | | 97 | | 52 | |
| 13 | 2010-07-03 | Tour de France | Prologue | | | 21 | | | 82 | | 8.9 | |
| 14 | 2010-06-25 | National Championships Spain ME - ITT | | | 1 | | | 2 | | 36.8 | |
| 15 | 2010-06-20 | Tour de Suisse | Stage 8 (ITT) | | | 19 | | | 42 | | 26.9 | |
| 16 | 2010-06-12 | Tour de Suisse | Prologue | | | 66 | | | 38 | | 7.6 | |
| 17 | 2010-03-22 | Volta Ciclista a Catalunya | Stage 1 (ITT) | | | 11 | | | 24 | | 3.6 | |
| 18 | 2010-03-07 | Paris - Nice | Prologue | | | 8 | | | 27 | | 8 | |
| 19 | 2009-07-23 | Tour de France | Stage 18 (ITT) | | | 7 | | | 40 | | 40.5 | |
| 20 | 2009-07-04 | Tour de France | Stage 1 (ITT) | | | 87 | | | 83 | | 15.5 | |
| 21 | 2009-06-26 | National Championships Spain ME - ITT | | | 2 | | | 5 | | 47.8 | |
| 22 | 2009-02-11 | Tour Méditerranéen Cycliste Professionnel | Stage 2 (TTT) | | | 5 | | | 1 | | 23.8 | |
| 23 | 2008-08-27 | Eneco Tour | Stage 8 (ITT) | | | 13 | | | 2 | | 18.8 | |
| 24 | 2008-08-20 | Eneco Tour | Prologue | | | 13 | | | 1 | | 4.4 | |
| 25 | 2008-07-26 | Tour de France | Stage 20 (ITT) | | | 32 | | | 60 | | 53 | |
| 26 | 2008-07-08 | Tour de France | Stage 4 (ITT) | | | 50 | | | 11 | | 29.5 | |
| 27 | 2008-06-25 | National Championships Spain ME - ITT | | | 1 | | | 3 | | 27.7 | |
| 28 | 2008-05-19 | Volta Ciclista a Catalunya | Prologue | | | 37 | | | 3 | | 3.7 | |
| 29 | 2007-09-27 | World Championships ME - ITT | | | 46 | | | 7 | | 44.9 | |
| 30 | 2007-06-27 | National Championships Spain ME - ITT | | | 2 | | | 1 | | 46.6 | |
| 31 | 2006-06-25 | National Championships Spain ME - ITT | | | 13 | | | 6 | | 36.7 | |
| 32 | 2005-06-24 | National Championships Spain ME - ITT | | | 4 | | | 1 | | 45.9 | |
| 33 | 2005-05-08 | Clásica Internacional Alcobendas | Stage 3 (ITT) | | | 1 | | | 2 | | 14.2 | |
| 34 | 2005-03-27 | Critérium International | Stage 3 (ITT) | | | 53 | | | 17 | | 8.3 | |
| 35 | 2004-06-25 | National Championships Spain ME - ITT | | | 2 | | | 1 | | 47.7 | |
| 36 | 2004-05-31 | Deutschland Tour | Stage 1 (ITT) | | | 19 | | | 11 | | 23 | |
| 37 | 2004-05-09 | Clásica Internacional Alcobendas | Stage 3 (ITT) | | | 1 | | | 8 | | 9.7 | |
| 38 | 2004-03-28 | Critérium International | Stage 3 (ITT) | | | 24 | | | 2 | | 8.3 | |
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