| 1 | 1968-07-28 | National Championships Spain - Road Race | | | 18 | | | 13 | | 75.5 | |
| 2 | 1967-05-13 | Vuelta a España | Stage 17 (ITT) | | | 14 | | | 39 | | 28 | |
| 3 | 1967-05-11 | Vuelta a España | Stage 15b (ITT) | | | 12 | | | 4 | | 44 | |
| 4 | 1967-04-27 | Vuelta a España | Stage 1b (ITT) | | | 12 | | | 19 | | 4.1 | |
| 5 | 1966-07-31 | National Championships Spain - Road Race | | | 1 | | | 2 | | 88 | |
| 6 | 1966-07-14 | Tour de France | Stage 22b (ITT) | | | 4 | | | 10 | | 51 | |
| 7 | 1966-07-05 | Tour de France | Stage 14b (ITT) | | | 61 | | | 16 | | 20 | |
| 8 | 1966-05-12 | Vuelta a España | Stage 15a (ITT) | | | 2 | | | 4 | | 61 | |
| 9 | 1966-04-28 | Vuelta a España | Stage 1b (ITT) | | | 27 | | | 32 | | 3.5 | |
| 10 | 1965-07-14 | Tour de France | Stage 22 (ITT) | | | 8 | | | 15 | | 37 | |
| 11 | 1965-07-10 | Tour de France | Stage 18 (ITT) | | | 29 | | | 32 | | 26 | |
| 12 | 1965-06-26 | Tour de France | Stage 5b (ITT) | | | 28 | | | 85 | | 26 | |
| 13 | 1965-05-14 | Vuelta a España | Stage 16 (ITT) | | | 19 | | | 7 | | 61 | |
| 14 | 1965-05-02 | Vuelta a España | Stage 4a (ITT) | | | 13 | | | 6 | | 41 | |
| 15 | 1964-09-19 | Volta Ciclista a Catalunya | Stage 7b (ITT) | | | 9 | | | 18 | | 18.9 | |
| 16 | 1964-09-15 | Volta Ciclista a Catalunya | Stage 3b (ITT) | | | 5 | | | 18 | | 6 | |
| 17 | 1964-05-14 | Vuelta a España | Stage 15 (ITT) | | | 7 | | | 21 | | 65 | |
| 18 | 1964-04-30 | Vuelta a España | Stage 1b (ITT) | | | 6 | | | 38 | | 11 | |
| 19 | 1964-04-18 | Eibarko Bizikleta | Stage 4 | | | 10 | | | 2 | | 92 | |
| | | | 13 | | | 6 | | | | |