| 1 | 1968-07-28 | National Championships Spain - Road Race | | | 18 | | | 20 |
| 2 | 1968-04-14 | GP Pascuas | | | 30 | | | 2 |
| 3 | 1967-07-12 | Tour de France | Stage 12 | | | 59 | | | DNF |
| 4 | 1967-07-11 | Tour de France | Stage 11 | | | 81 | | | 86 |
| 5 | 1967-07-10 | Tour de France | Stage 10 | | | 80 | | | 82 |
| 6 | 1967-07-09 | Tour de France | Stage 9 | | | 60 | | | 56 |
| 7 | 1967-07-07 | Tour de France | Stage 8 | | | 87 | | | 76 |
| 8 | 1967-07-06 | Tour de France | Stage 7 | | | 95 | | | 47 |
| 9 | 1967-07-05 | Tour de France | Stage 6 | | | 48 | | | 89 |
| 10 | 1967-07-04 | Tour de France | Stage 5a | | | 52 | | | 107 |
| 11 | 1967-07-03 | Tour de France | Stage 4 | | | 45 | | | 47 |
| 12 | 1967-07-02 | Tour de France | Stage 3 | | | 79 | | | 36 |
| 13 | 1967-07-01 | Tour de France | Stage 2 | | | 88 | | | 5 |
| 14 | 1967-06-30 | Tour de France | Stage 1 | | | 116 | | | 43 |
| 15 | 1967-06-29 | Tour de France | Prologue | | | 4 | | | 17 |
| 16 | 1967-06-24 | Tour de Suisse | General classification | | | 34 | | | 17 |
| 17 | 1967-03-27 | GP Pascuas | | | 31 | | | 4 |
| 18 | 1967-03-18 | Milano-Sanremo | | | 63 | | | 34 |
| 19 | 1967-02-19 | Vuelta a Andalucia Ruta Ciclista Del Sol | General classification | | | 17 | | | 6 |
| 20 | 1966-05-09 | Vuelta a España | Stage 12 | | | 14 | | | 23 |
| 21 | 1966-05-08 | Vuelta a España | Stage 11 | | | 21 | | | 9 |
| 22 | 1966-05-07 | Vuelta a España | Stage 10b | | | 18 | | | 11 |
| 23 | 1966-05-07 | Vuelta a España | Stage 10a | | | 1 | | | 12 |
| 24 | 1966-05-06 | Vuelta a España | Stage 9 | | | 23 | | | 3 |
| 25 | 1966-05-05 | Vuelta a España | Stage 8 | | | 60 | | | 35 |
| 26 | 1966-05-04 | Vuelta a España | Stage 7 | | | 16 | | | 24 |
| 27 | 1966-05-03 | Vuelta a España | Stage 6 | | | 72 | | | 5 |
| 28 | 1966-05-02 | Vuelta a España | Stage 5 | | | 38 | | | 3 |
| 29 | 1966-05-01 | Vuelta a España | Stage 4 | | | 25 | | | 25 |
| 30 | 1966-04-30 | Vuelta a España | Stage 3 | | | 16 | | | 16 |
| 31 | 1966-04-28 | Vuelta a España | Stage 1b (ITT) | | | 27 | | | 23 |
| 32 | 1966-04-28 | Vuelta a España | Stage 1a | | | 9 | | | 9 |
| 33 | 1966-03-29 | Barcelona - Andorra | | | 14 | | | 5 |
| 34 | 1965-05-16 | Vuelta a España | General classification | | | 14 | | | 24 |
| 35 | 1965-05-16 | Vuelta a España | Stage 18 | | | 17 | | | 16 |
| 36 | 1965-05-15 | Vuelta a España | Stage 17 | | | 10 | | | 3 |
| 37 | 1965-05-14 | Vuelta a España | Stage 16 (ITT) | | | 19 | | | 22 |
| 38 | 1965-05-13 | Vuelta a España | Stage 15 | | | 20 | | | 9 |
| 39 | 1965-05-12 | Vuelta a España | Stage 14 | | | 5 | | | 6 |
| 40 | 1965-05-11 | Vuelta a España | Stage 13 | | | 33 | | | 16 |
| 41 | 1965-05-10 | Vuelta a España | Stage 12 | | | 23 | | | 47 |
| 42 | 1965-05-09 | Vuelta a España | Stage 11 | | | 27 | | | 42 |
| 43 | 1965-05-08 | Vuelta a España | Stage 10a | | | 28 | | | 6 |
| 44 | 1965-05-08 | Vuelta a España | Stage 10b | | | 24 | | | 13 |
| 45 | 1965-05-07 | Vuelta a España | Stage 9 | | | 12 | | | 4 |
| 46 | 1965-05-06 | Vuelta a España | Stage 8 | | | 37 | | | 45 |
| 47 | 1965-05-05 | Vuelta a España | Stage 7 | | | 6 | | | 6 |
| 48 | 1965-05-04 | Vuelta a España | Stage 6 | | | 17 | | | 19 |
| 49 | 1965-05-03 | Vuelta a España | Stage 5 | | | 17 | | | 57 |
| 50 | 1965-05-02 | Vuelta a España | Stage 4a (ITT) | | | 13 | | | 60 |
| 51 | 1965-05-02 | Vuelta a España | Stage 4b | | | 20 | | | 53 |
| 52 | 1965-05-01 | Vuelta a España | Stage 3 | | | 15 | | | 39 |
| 53 | 1965-04-30 | Vuelta a España | Stage 2 | | | 14 | | | 8 |
| 54 | 1965-04-29 | Vuelta a España | Stage 1 | | | 27 | | | 59 |
| 55 | 1965-03-19 | Milano-Sanremo | | | 27 | | | 41 |
| 56 | 1965-03-16 | Barcelona - Andorra | | | 8 | | | 1 |
| 57 | 1965-03-14 | Setmana Catalana | General classification | | | 7 | | | 4 |
| 58 | 1965-03-07 | Vuelta a Levante | General classification | | | 25 | | | 13 |
| 59 | 1964-08-29 | Paris - Luxembourg | Stage 1 | | | 29 | | | DNF |
| 60 | 1964-08-23 | National Championships Spain - Road Race | | | 3 | | | 17 |
| 61 | 1963-09-15 | Volta Ciclista a Catalunya | General classification | | | 26 | | | 12 |
| 62 | 1963-09-13 | Volta Ciclista a Catalunya | Stage 6 | | | 4 | | | 1 |
| 63 | 1963-07-21 | National Championships Spain - Road Race | | | DNF | | | DNF |
| 64 | 1962-08-05 | National Championships Spain - Road Race | | | 1 | | | DNF |
| 65 | 1962-07-12 | Tour de France | Stage 19 | | | 38 | | | DNF |
| 66 | 1962-07-11 | Tour de France | Stage 18 | | | 37 | | | 59 |
| 67 | 1962-07-10 | Tour de France | Stage 17 | | | 86 | | | 18 |
| 68 | 1962-07-09 | Tour de France | Stage 16 | | | 76 | | | 42 |
| 69 | 1962-07-08 | Tour de France | Stage 15 | | | 81 | | | 41 |
| 70 | 1962-07-07 | Tour de France | Stage 14 | | | 66 | | | 92 |
| 71 | 1962-07-06 | Tour de France | Stage 13 (ITT) | | | 16 | | | 76 |
| 72 | 1962-07-05 | Tour de France | Stage 12 | | | 17 | | | 76 |
| 73 | 1962-07-04 | Tour de France | Stage 11 | | | 40 | | | 63 |
| 74 | 1962-07-03 | Tour de France | Stage 10 | | | 42 | | | 32 |
| 75 | 1962-07-02 | Tour de France | Stage 9 | | | 60 | | | 119 |
| 76 | 1962-07-01 | Tour de France | Stage 8b (ITT) | | | 22 | | | 71 |
| 77 | 1962-07-01 | Tour de France | Stage 8a | | | 19 | | | 13 |
| 78 | 1962-06-30 | Tour de France | Stage 7 | | | 69 | | | 41 |
| 79 | 1962-06-29 | Tour de France | Stage 6 | | | 46 | | | 21 |
| 80 | 1962-06-28 | Tour de France | Stage 5 | | | 75 | | | 41 |
| 81 | 1962-06-27 | Tour de France | Stage 4 | | | 72 | | | 105 |
| 82 | 1962-06-26 | Tour de France | Stage 3 | | | 44 | | | 67 |
| 83 | 1962-06-25 | Tour de France | Stage 2a | | | 44 | | | 17 |
| 84 | 1962-06-24 | Tour de France | Stage 1 | | | 8 | | | 128 |
| 85 | 1962-05-01 | GP Stan Ockers | | | 57 | | | 15 |
| 86 | 1961-06-26 | Tour de France | Stage 2 | | | 5 | | | OTL |
| 87 | 1961-06-25 | Tour de France | Stage 1b (ITT) | | | 12 | | | 128 |
| 88 | 1961-06-25 | Tour de France | Stage 1a | | | 49 | | | 87 |
| 89 | 1960-10-02 | Paris - Tours | | | 3 | | | 31 |
| 90 | 1960-06-12 | National Championships Spain - Road Race | | | 5 | | | 10 |
| 91 | 1960-05-22 | Tour du Sud-Est | General classification | | | 7 | | | 26 |
| 92 | 1960-03-16 | Paris - Nice | General classification | | | 21 | | | 34 |
| 93 | 1959-09-13 | Volta Ciclista a Catalunya | General classification | | | 9 | | | 10 |
| 94 | 1959-09-09 | Volta Ciclista a Catalunya | Stage 5a (ITT) | | | 8 | | | 10 |
| | | | 47 | | | 42 | |