| 1 | 2015-07-04 | Tour de France | Stage 1 (ITT) | | | 34 | | | 29 | | 13.8 | |
| 2 | 2015-05-23 | Giro d'Italia | Stage 14 (ITT) | | | 112 | | | 11 | | 59.4 | |
| 3 | 2014-07-26 | Tour de France | Stage 20 (ITT) | | | 78 | | | 8 | | 54 | |
| 4 | 2013-07-17 | Tour de France | Stage 17 (ITT) | | | 13 | | | 29 | | 32 | |
| 5 | 2013-07-10 | Tour de France | Stage 11 (ITT) | | | 20 | | | 7 | | 33 | |
| 6 | 2013-06-05 | Critérium du Dauphiné | Stage 4 (ITT) | | | 14 | | | 18 | | 32.5 | |
| 7 | 2013-05-17 | Amgen Tour of California | Stage 6 (ITT) | | | 4 | | | 10 | | 31.6 | |
| 8 | 2012-08-01 | Olympic Games - ITT | | | 6 | | | 29 | | 44 | |
| 9 | 2012-07-09 | Tour de France | Stage 9 (ITT) | | | 27 | | | 5 | | 41.5 | |
| 10 | 2012-06-30 | Tour de France | Prologue | | | 61 | | | 3 | | 6.4 | |
| 11 | 2012-06-07 | Critérium du Dauphiné | Stage 4 (ITT) | | | 3 | | | 5 | | 53.5 | |
| 12 | 2012-06-03 | Critérium du Dauphiné | Prologue | | | 24 | | | 8 | | 5.7 | |
| 13 | 2011-03-11 | Paris - Nice | Stage 6 (ITT) | | | 22 | | | 32 | | 27 | |
| 14 | 2011-02-20 | Volta ao Algarve | Stage 5 (ITT) | | | DNF | | | 10 | | 17.2 | |
| 15 | 2010-09-30 | World Championships ME - ITT | | | 5 | | | 19 | | 45.4 | |
| 16 | 2010-07-24 | Tour de France | Stage 19 (ITT) | | | 92 | | | 47 | | 52 | |
| 17 | 2010-07-03 | Tour de France | Prologue | | | 13 | | | 86 | | 8.9 | |
| 18 | 2010-06-12 | Tour de Suisse | Prologue | | | 12 | | | 83 | | 7.6 | |
| 19 | 2009-08-25 | Eneco Tour | Stage 8 (ITT) | | | 14 | | | 4 | | 13.1 | |
| 20 | 2009-08-18 | Eneco Tour | Prologue | | | 29 | | | 1 | | 4.4 | |
| 21 | 2009-07-23 | Tour de France | Stage 18 (ITT) | | | 19 | | | 14 | | 40.5 | |
| 22 | 2009-07-04 | Tour de France | Stage 1 (ITT) | | | 26 | | | 15 | | 15.5 | |
| 23 | 2008-09-25 | World Championships ME - ITT | | | 12 | | | 10 | | 43.7 | |
| 24 | 2008-05-19 | Volta Ciclista a Catalunya | Prologue | | | 23 | | | 10 | | 3.7 | |
| 25 | 2007-07-07 | Tour de France | Prologue | | | 20 | | | 19 | | 7.9 | |
| 26 | 2007-05-25 | Volta Ciclista a Catalunya | Stage 5 (ITT) | | | 5 | | | 43 | | 17.1 | |
| 27 | 2006-07-22 | Tour de France | Stage 19 (ITT) | | | 17 | | | 14 | | 57 | |
| 28 | 2006-07-08 | Tour de France | Stage 7 (ITT) | | | 3 | | | 25 | | 52 | |
| 29 | 2006-07-01 | Tour de France | Prologue | | | 6 | | | 40 | | 7.1 | |
| 30 | 2005-09-22 | World Championships ME - ITT | | | 1 | | | 30 | | 44.1 | |
| 31 | 2005-07-23 | Tour de France | Stage 20 (ITT) | | | 30 | | | 64 | | 55 | |
| 32 | 2005-07-02 | Tour de France | Stage 1 (ITT) | | | 45 | | | 73 | | 19 | |
| 33 | 2005-05-20 | Volta Ciclista a Catalunya | Stage 5 (ITT) | | | 6 | | | 36 | | 17.1 | |
| 34 | 2005-03-06 | Paris - Nice | Prologue | | | 10 | | | 5 | | 4 | |
| 35 | 2004-07-24 | Tour de France | Stage 19 (ITT) | | | 50 | | | 28 | | 55 | |
| 36 | 2004-07-21 | Tour de France | Stage 16 (ITT) | | | 12 | | | 25 | | 15.5 | |
| 37 | 2004-07-03 | Tour de France | Prologue | | | 121 | | | 52 | | 6.1 | |
| 38 | 2004-03-07 | Paris - Nice | Stage 1 (ITT) | | | 20 | | | 89 | | 13.2 | |
| 39 | 2003-10-09 | World Championships ME - ITT | | | 1 | | | 19 | | 41.6 | |
| 40 | 2003-07-26 | Tour de France | Stage 19 (ITT) | | | 12 | | | 9 | | 49 | |
| 41 | 2003-07-18 | Tour de France | Stage 12 (ITT) | | | 22 | | | 108 | | 47 | |
| 42 | 2003-07-05 | Tour de France | Prologue | | | 19 | | | 105 | | 6.5 | |
| 43 | 2003-04-10 | Circuit de la Sarthe | Stage 3b (ITT) | | | 6 | | | 1 | | 8.8 | |
| 44 | 2002-08-30 | Tour du Poitou Charentes et de la Vienne | Stage 4 (ITT) | | | DF | | | DF | | 23.9 | |
| 45 | 1997-10-07 | World Championships MJ - ITT | | | 2 | | | 18 | | 0 | |
| | | | 22 | | | 23 | | | | |