| 1 | 1960 | | Volta Ciclista a Catalunya | Stage 1 (ITT) | 1 |
| 2 | 1964 | | Volta Ciclista a Catalunya | Stage 7b (ITT) | 1 |
| 3 | 1965 | | Volta Ciclista a Catalunya | Stage 6b (ITT) | 1 |
| 4 | 1969 | | Vuelta a España | Stage 1a (ITT) | 2 |
| 5 | 1964 | | Volta Ciclista a Catalunya | Stage 3b (ITT) | 2 |
| 6 | 1966 | | Vuelta a España | Stage 1b (ITT) | 4 |
| 7 | 1967 | | Vuelta a España | Stage 1b (ITT) | 4 |
| 8 | 1960 | | Vuelta a Levante | Stage 4a (ITT) | 1 |
| 9 | 1966 | | Tour de France | Stage 14b (ITT) | 8 |
| 10 | 1965 | | Tour de France | Stage 5b (ITT) | 9 |
| 11 | 1968 | | Tour de France | Prologue | 9 |
| 12 | 1965 | | Volta Ciclista a Catalunya | Stage 1 (ITT) | 4 |
| 13 | 1966 | | Volta Ciclista a Catalunya | Stage 6b (ITT) | 4 |
| 14 | 1967 | | Volta Ciclista a Catalunya | Stage 7b (ITT) | 4 |
| 15 | 1961 | | Madrid - Barcelona | Stage 6b (ITT) | 2 |
| 16 | 1963 | | Vuelta a España | Stage 12b (ITT) | 7 |
| 17 | 1964 | | Vuelta a Levante | Stage 4 (ITT) | 2 |
| 18 | 1966 | | Vuelta a España | Stage 15a (ITT) | 7 |
| 19 | 1971 | | Vuelta Asturias | Prologue | 2 |
| 20 | 1963 | | Vuelta a España | Stage 1b (ITT) | 8 |
| 21 | 1965 | | Volta Ciclista a Catalunya | Stage 5a (ITT) | 5 |
| 22 | 1968 | | National Championships Spain - Road Race | 2 |
| 23 | 1971 | | Vuelta a España | Prologue | 8 |
| 24 | 1960 | | Volta Ciclista a Catalunya | Stage 8a (ITT) | 6 |
| 25 | 1965 | | Vuelta a España | Stage 16 (ITT) | 10 |
| 26 | 1967 | | Vuelta a España | Stage 15b (ITT) | 10 |
| 27 | 1971 | | Vuelta a España | Stage 17b (ITT) | 11 |
| 28 | 1971 | | Vuelta Asturias | Stage 5b | 5 |
| 29 | 1964 | | Giro d'Italia | Stage 5 (ITT) | 13 |
| 30 | 1961 | | Vuelta a España | Stage 12 (ITT) | 15 |
| 31 | 1962 | | Tour de l'Avenir | Stage 5 (ITT) | 3 |
| 32 | 1965 | | Vuelta a España | Stage 4a (ITT) | 15 |
| 33 | 1965 | | Escalada a Montjuïc | Stage 1b (ITT) | 8 |
| 34 | 1968 | | Tour de France | Stage 22b (ITT) | 15 |
| 35 | 1970 | | Vuelta Ciclista al País Vasco | Stage 3b (ITT) | 10 |
| 36 | 1962 | | Vuelta a España | Stage 15 (ITT) | 41 |
| 37 | 1963 | | Tour de France | Stage 6b (ITT) | 17 |
| 38 | 1963 | | Tour de France | Stage 19 (ITT) | 16 |
| 39 | 1965 | | Vuelta a Levante | Stage 2 (ITT) | 10 |
| 40 | 1966 | | Tour de France | Stage 22b (ITT) | 16 |
| 41 | 1966 | | Escalada a Montjuïc | Stage 1b (ITT) | 10 |
| 42 | 1967 | | Vuelta a España | Stage 17 (ITT) | 25 |
| 43 | 1967 | | Giro d'Italia | Stage 16 (ITT) | 21 |
| 44 | 1969 | | Tour de France | Prologue | 17 |
| 45 | 1970 | | Vuelta a España | Prologue | 31 |
| 46 | 1970 | | Vuelta a España | Stage 19b (ITT) | 24 |
| 47 | 1972 | | Vuelta a España | Prologue | 23 |
| 48 | 1972 | | Vuelta a España | Stage 9b (ITT) | 27 |
| 49 | 1972 | | Vuelta a España | Stage 17b (ITT) | 40 |
| 50 | 1972 | | Volta Ciclista a Catalunya | Stage 5b (ITT) | 22 |