| 1 | 2021-07-17 | Tour de France | Stage 20 (ITT) | | | 63 | | | 73 | | 30.8 | |
| 2 | 2021-06-30 | Tour de France | Stage 5 (ITT) | | | 148 | | | 80 | | 27.2 | |
| 3 | 2019-09-03 | La Vuelta ciclista a España | Stage 10 (ITT) | | | 46 | | | 13 | | 36.2 | |
| 4 | 2017-07-01 | Tour de France | Stage 1 (ITT) | | | 21 | | | DNF | | 14 | |
| 5 | 2016-02-20 | Vuelta a Andalucia Ruta Ciclista Del Sol | Stage 4 (ITT) | | | 60 | | | 8 | | 21 | |
| 6 | 2015-02-10 | Tour of Qatar | Stage 3 (ITT) | | | 31 | | | 19 | | 10.9 | |
| 7 | 2014-09-14 | Vuelta a España | Stage 21 (ITT) | | | 146 | | | 32 | | 9.7 | |
| 8 | 2014-09-02 | Vuelta a España | Stage 10 (ITT) | | | 51 | | | 8 | | 36.7 | |
| 9 | 2014-04-12 | Vuelta Ciclista al País Vasco | Stage 6 (ITT) | | | 25 | | | 8 | | 25.9 | |
| 10 | 2013-09-04 | Vuelta a España | Stage 11 (ITT) | | | 48 | | | 7 | | 38.8 | |
| 11 | 2013-07-17 | Tour de France | Stage 17 (ITT) | | | 50 | | | 5 | | 32 | |
| 12 | 2013-07-10 | Tour de France | Stage 11 (ITT) | | | 38 | | | 13 | | 33 | |
| 13 | 2012-08-29 | Vuelta a España | Stage 11 (ITT) | | | 14 | | | 4 | | 39.4 | |
| 14 | 2012-07-21 | Tour de France | Stage 19 (ITT) | | | 121 | | | 113 | | 53.5 | |
| 15 | 2012-07-09 | Tour de France | Stage 9 (ITT) | | | 31 | | | 34 | | 41.5 | |
| 16 | 2012-06-30 | Tour de France | Prologue | | | 9 | | | 116 | | 6.4 | |
| 17 | 2010-04-30 | Tour de Romandie | Stage 3 (ITT) | | | 51 | | | 2 | | 23.4 | |
| 18 | 2010-04-27 | Tour de Romandie | Prologue | | | 24 | | | 13 | | 4.3 | |
| 19 | 2010-03-07 | Paris - Nice | Prologue | | | 90 | | | 31 | | 8 | |
| 20 | 2009-09-19 | Vuelta a España | Stage 20 (ITT) | | | 6 | | | 7 | | 27.8 | |
| 21 | 2009-09-05 | Vuelta a España | Stage 7 (ITT) | | | 21 | | | 13 | | 30.3 | |
| 22 | 2009-08-29 | Vuelta a España | Prologue | | | 14 | | | 9 | | 4.8 | |
| 23 | 2009-04-28 | Tour de Romandie | Prologue | | | 14 | | | 3 | | 3.1 | |
| 24 | 2008-09-03 | Vuelta a España | Stage 5 (ITT) | | | 161 | | | 5 | | 42.5 | |
| 25 | 2008-07-26 | Tour de France | Stage 20 (ITT) | | | 108 | | | 33 | | 53 | |
| 26 | 2008-07-08 | Tour de France | Stage 4 (ITT) | | | 86 | | | 22 | | 29.5 | |
| 27 | 2007-07-21 | Tour de France | Stage 13 (ITT) | | | 123 | | | 46 | | 54 | |
| 28 | 2007-07-07 | Tour de France | Prologue | | | 43 | | | 32 | | 7.9 | |
| 29 | 2007-06-13 | Critérium du Dauphiné Libéré | Stage 3 (ITT) | | | 49 | | | 9 | | 40.7 | |
| 30 | 2007-06-10 | Critérium du Dauphiné Libéré | Prologue | | | 32 | | | 5 | | 4.2 | |
| 31 | 2006-07-01 | Tour de France | Prologue | | | 71 | | | 4 | | 7.1 | |
| 32 | 2006-06-07 | Critérium du Dauphiné Libéré | Stage 3 (ITT) | | | 14 | | | 7 | | 43 | |
| 33 | 2006-06-04 | Critérium du Dauphiné Libéré | Prologue | | | 24 | | | 7 | | 4.1 | |
| 34 | 2005-07-02 | Tour de France | Stage 1 (ITT) | | | 165 | | | 82 | | 19 | |
| 35 | 2005-05-20 | Volta Ciclista a Catalunya | Stage 5 (ITT) | | | 94 | | | 18 | | 17.1 | |
| 36 | 2005-04-08 | Vuelta al País Vasco | Stage 5b (ITT) | | | 109 | | | 39 | | 9.3 | |
| 37 | 2005-03-06 | Paris - Nice | Prologue | | | 13 | | | 41 | | 4 | |
| | | | 6 | | | 31 | | | | |