| 1 | 1966 | | Vuelta a España | Stage 15a (ITT) | 2 |
| 2 | 1966 | | Tour de France | Stage 22b (ITT) | 4 |
| 3 | 1967 | | Tour de France | Prologue | 4 |
| 4 | 1959 | | Vuelta a España | Stage 14 (ITT) | 3 |
| 5 | 1960 | | Grand Prix des Nations | 11 |
| 6 | 1965 | | Tour de France | Stage 22 (ITT) | 8 |
| 7 | 1961 | | Vuelta a España | Stage 12 (ITT) | 6 |
| 8 | 1964 | | Vuelta a España | Stage 1b (ITT) | 6 |
| 9 | 1966 | | National Championships Spain - Road Race | 1 |
| 10 | 1968 | | Tour de Suisse | Stage 9b (ITT) | 4 |
| 11 | 1960 | | 4 Jours de Dunkerque / Tour du Nord-pas-de-Calais | Stage 3b (ITT) | 3 |
| 12 | 1964 | | Vuelta a España | Stage 15 (ITT) | 7 |
| 13 | 1958 | | Vuelta a España | Stage 13a (ITT) | 8 |
| 14 | 1964 | | Volta Ciclista a Catalunya | Stage 3b (ITT) | 5 |
| 15 | 1957 | | Volta Ciclista a Catalunya | Stage 3b (ITT) | 6 |
| 16 | 1963 | | Paris - Nice | Stage 6a (ITT) | 6 |
| 17 | 1961 | | Tour de France | Stage 1b (ITT) | 12 |
| 18 | 1968 | | Vuelta a Mallorca | Stage 4b | 4 |
| 19 | 1960 | | Paris - Nice | Stage 6b (ITT) | 7 |
| 20 | 1967 | | Vuelta a España | Stage 1b (ITT) | 12 |
| 21 | 1967 | | Vuelta a España | Stage 15b (ITT) | 12 |
| 22 | 1959 | | Volta Ciclista a Catalunya | Stage 5a (ITT) | 8 |
| 23 | 1960 | | GP de Fourmies / La Voix du Nord | Stage 1 (ITT) | 6 |
| 24 | 1965 | | Vuelta a España | Stage 4a (ITT) | 13 |
| 25 | 1960 | | National Championships Spain - Road Race | 5 |
| 26 | 1964 | | Volta Ciclista a Catalunya | Stage 7b (ITT) | 9 |
| 27 | 1967 | | Vuelta a España | Stage 17 (ITT) | 14 |
| 28 | 1960 | | Eibarko Bizikleta | Stage 1 (ITT) | 8 |
| 29 | 1958 | | Tour de France | Stage 8 (ITT) | 36 |
| 30 | 1958 | | Tour de France | Stage 18 (ITT) | 40 |
| 31 | 1958 | | Tour de France | Stage 23 (ITT) | 53 |
| 32 | 1959 | | National Championships Spain - Road Race | 20 |
| 33 | 1959 | | Tour de France | Stage 6 (ITT) | 18 |
| 34 | 1960 | | Tour de France | Stage 1b (ITT) | 110 |
| 35 | 1960 | | Tour de France | Stage 19 (ITT) | 18 |
| 36 | 1961 | | Eibarko Bizikleta | Stage 1 (ITT) | 9 |
| 37 | 1961 | | Tour de France | Stage 19 (ITT) | 30 |
| 38 | 1962 | | Tour de France | Stage 8b (ITT) | 22 |
| 39 | 1962 | | Tour de France | Stage 13 (ITT) | 16 |
| 40 | 1962 | | Tour de France | Stage 20 (ITT) | 17 |
| 41 | 1963 | | Tour du Sud-Est | Stage 4b (ITT) | 10 |
| 42 | 1963 | | Tour de France | Stage 6b (ITT) | 21 |
| 43 | 1963 | | Tour de France | Stage 19 (ITT) | 25 |
| 44 | 1964 | | Eibarko Bizikleta | Stage 4 | 10 |
| 45 | 1964 | | Tour de France | Stage 10b (ITT) | 81 |
| 46 | 1964 | | Tour de France | Stage 17 (ITT) | 22 |
| 47 | 1964 | | Tour de France | Stage 22b (ITT) | 80 |
| 48 | 1965 | | Vuelta a España | Stage 16 (ITT) | 19 |
| 49 | 1965 | | Tour de France | Stage 5b (ITT) | 28 |
| 50 | 1965 | | Tour de France | Stage 18 (ITT) | 29 |
| 51 | 1966 | | Vuelta a España | Stage 1b (ITT) | 27 |
| 52 | 1966 | | Tour de France | Stage 14b (ITT) | 61 |
| 53 | 1967 | | Volta Ciclista a Catalunya | Stage 7b (ITT) | 13 |
| 54 | 1968 | | National Championships Spain - Road Race | 18 |