| 1 | 2011-07-23 | Tour de France | Stage 20 (ITT) | | | 103 | | | 90 | | 42.5 | |
| 2 | 2011-03-15 | Tirreno-Adriatico | Stage 7 (ITT) | | | 112 | | | 25 | | 9.3 | |
| 3 | 2010-07-24 | Tour de France | Stage 19 (ITT) | | | 121 | | | 24 | | 52 | |
| 4 | 2010-07-03 | Tour de France | Prologue | | | 154 | | | 84 | | 8.9 | |
| 5 | 2009-07-23 | Tour de France | Stage 18 (ITT) | | | 119 | | | 29 | | 40.5 | |
| 6 | 2009-07-04 | Tour de France | Stage 1 (ITT) | | | 118 | | | 117 | | 15.5 | |
| 7 | 2009-05-18 | Volta Ciclista a Catalunya | Stage 1 (ITT) | | | 1 | | | 49 | | 3.6 | |
| 8 | 2008-07-26 | Tour de France | Stage 20 (ITT) | | | 120 | | | 7 | | 53 | |
| 9 | 2008-07-08 | Tour de France | Stage 4 (ITT) | | | 110 | | | 18 | | 29.5 | |
| 10 | 2008-06-11 | Critérium du Dauphiné Libéré | Stage 4 (ITT) | | | 98 | | | 31 | | 31 | |
| 11 | 2008-06-08 | Critérium du Dauphiné Libéré | Prologue | | | 2 | | | 23 | | 5.6 | |
| 12 | 2008-05-19 | Volta Ciclista a Catalunya | Prologue | | | 1 | | | 35 | | 3.7 | |
| 13 | 2007-08-29 | Eneco Tour | Stage 7 (ITT) | | | 28 | | | 9 | | 29.6 | |
| 14 | 2007-08-22 | Eneco Tour | Prologue | | | 132 | | | 122 | | 5.2 | |
| 15 | 2007-03-18 | Tirreno-Adriatico | Stage 5 (ITT) | | | 130 | | | DNS | | 20.5 | |
| 16 | 2006-07-22 | Tour de France | Stage 19 (ITT) | | | 69 | | | 4 | | 57 | |
| 17 | 2006-07-08 | Tour de France | Stage 7 (ITT) | | | 138 | | | 2 | | 52 | |
| 18 | 2006-07-01 | Tour de France | Prologue | | | 1 | | | 3 | | 7.1 | |
| 19 | 2006-06-07 | Critérium du Dauphiné Libéré | Stage 3 (ITT) | | | 59 | | | 8 | | 43 | |
| 20 | 2006-06-04 | Critérium du Dauphiné Libéré | Prologue | | | 14 | | | 4 | | 4.1 | |
| 21 | 2006-05-15 | Volta Ciclista a Catalunya | Stage 1 (ITT) | | | 14 | | | 9 | | 12.6 | |
| 22 | 2005-07-23 | Tour de France | Stage 20 (ITT) | | | 80 | | | 16 | | 55 | |
| 23 | 2005-07-02 | Tour de France | Stage 1 (ITT) | | | 153 | | | 21 | | 19 | |
| 24 | 2005-06-08 | Critérium du Dauphiné Libéré | Stage 3 (ITT) | | | 45 | | | 10 | | 46.5 | |
| 25 | 2005-06-05 | Critérium du Dauphiné Libéré | Prologue | | | 43 | | | 42 | | 7.9 | |
| 26 | 2005-05-20 | Volta Ciclista a Catalunya | Stage 5 (ITT) | | | 152 | | | 48 | | 17.1 | |
| 27 | 2004-07-24 | Tour de France | Stage 19 (ITT) | | | 79 | | | 39 | | 55 | |
| 28 | 2004-07-21 | Tour de France | Stage 16 (ITT) | | | 127 | | | 102 | | 15.5 | |
| 29 | 2004-07-03 | Tour de France | Prologue | | | 5 | | | 36 | | 6.1 | |
| 30 | 2003-03-13 | Paris - Nice | Stage 4 (ITT) | | | 85 | | | 38 | | 16.5 | |
| 31 | 2003-03-09 | Paris - Nice | Prologue | | | 11 | | | 44 | | 4.8 | |
| 32 | 1999-08-13 | European Continental Championships MU - ITT | | | 12 | | | 10 | | 30.2 | |
| | | | 7 | | | 25 | | | | |