| 1 | 2011-08-29 | Vuelta a España | Stage 10 (ITT) | | | 19 | | | 38 | | 47 | |
| 2 | 2011-07-23 | Tour de France | Stage 20 (ITT) | | | 28 | | | 90 | | 42.5 | |
| 3 | 2010-07-03 | Tour de France | Prologue | | | 25 | | | 84 | | 8.9 | |
| 4 | 2010-05-30 | Giro d'Italia | Stage 21 (ITT) | | | 20 | | | 64 | | 15.3 | |
| 5 | 2010-05-25 | Giro d'Italia | Stage 16 (ITT) | | | 36 | | | 69 | | 12.9 | |
| 6 | 2010-05-08 | Giro d'Italia | Stage 1 (ITT) | | | 35 | | | 58 | | 8.4 | |
| 7 | 2009-07-23 | Tour de France | Stage 18 (ITT) | | | 15 | | | 29 | | 40.5 | |
| 8 | 2009-07-04 | Tour de France | Stage 1 (ITT) | | | 21 | | | 117 | | 15.5 | |
| 9 | 2009-05-18 | Volta Ciclista a Catalunya | Stage 1 (ITT) | | | 14 | | | 49 | | 3.6 | |
| 10 | 2009-04-28 | Tour de Romandie | Prologue | | | 24 | | | 131 | | 3.1 | |
| 11 | 2007-09-27 | World Championships ME - ITT | | | 21 | | | 5 | | 44.9 | |
| 12 | 2007-05-25 | Volta Ciclista a Catalunya | Stage 5 (ITT) | | | 2 | | | 120 | | 17.1 | |
| 13 | 2006-07-22 | Tour de France | Stage 19 (ITT) | | | 22 | | | 4 | | 57 | |
| 14 | 2006-07-08 | Tour de France | Stage 7 (ITT) | | | 11 | | | 2 | | 52 | |
| 15 | 2006-07-01 | Tour de France | Prologue | | | 8 | | | 3 | | 7.1 | |
| 16 | 2006-05-15 | Volta Ciclista a Catalunya | Stage 1 (ITT) | | | 2 | | | 9 | | 12.6 | |
| 17 | 2005-07-23 | Tour de France | Stage 20 (ITT) | | | 10 | | | 16 | | 55 | |
| 18 | 2005-07-02 | Tour de France | Stage 1 (ITT) | | | 9 | | | 21 | | 19 | |
| 19 | 2004-07-24 | Tour de France | Stage 19 (ITT) | | | 8 | | | 39 | | 55 | |
| 20 | 2004-07-21 | Tour de France | Stage 16 (ITT) | | | 7 | | | 102 | | 15.5 | |
| 21 | 2004-07-03 | Tour de France | Prologue | | | 30 | | | 36 | | 6.1 | |
| | | | 17 | | | 4 | | | | |